Direct Synthesis Sulfonamides from Nitroarenes and Sulfonyl Chlorides in Water

doi:10.6023/cjoc201807033

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (2): 463-468.DOI: 10.6023/cjoc201807033 Previous Articles Next Articles

ARTICLE

通过硝基苯与磺酰氯水相反应直接合成磺酰胺

岳会兰^a, 鲍鹏丽^b, 王雷雷^b, 吕晓霞^b, 杨道山^b, 王桦^b, 魏伟^a,b

a 中国科学院藏药研究重点实验室中国科学院西北高原生物研究所西宁 810008;
b 曲阜师范大学化学与化工学院曲阜 273165

收稿日期:2018-07-21 修回日期:2018-08-31 发布日期:2018-09-18
通讯作者: 魏伟 E-mail:weiweiqfnu@163.com
基金资助:
青海省国际科技合作专项基金（Nos.2018-HZ-806，2017-HZ-806）、青海省藏药重点实验室（Nos.2017-ZJ-Y11）、山东省自然科学基金（Nos.ZR2018MB009，ZR2016JL012）、国家自然科学基金（Nos.21302109，21302110，21601106）资助项目.

Direct Synthesis Sulfonamides from Nitroarenes and Sulfonyl Chlorides in Water

Yue Huilan^a, Bao Pengli^b, Wang Leilei^b, Lü Xiaoxia^b, Yang Daoshan^b, Wang Hua^b, Wei Wei^a,b

a Key Laboratory of Tibetan Medicine Research, Northwest Institute of Plateau Biology, Chinese Academy of Sciences, Qinghai 810008;
b School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165

Received:2018-07-21 Revised:2018-08-31 Published:2018-09-18
Contact: 10.6023/cjoc201807033 E-mail:weiweiqfnu@163.com
Supported by:
Project supported by the International Cooperation Project of Qinghai Province (Nos. 2018-HZ-806, 2017-HZ-806), the Qinghai Key Laboratory of Tibetan Medicine Research (No. 2017-ZJ-Y11), the Natural Science Foundation of Shandong Province (Nos. ZR2018MB009, ZR2016JL012), and the National Natural Science Foundation of China (Nos. 21302109, 21302110, 21601106).

1. Direct Synthesis Sulfonamides from Nitroarenes and Sulfonyl Chlorides in Water.PDF(1880KB)

Abstract

A simple and practical route for construction of various sulfonamides from nitroarenes and sulfonyl chlorides with iron powder as the sole reductant in water (green solvent) under open-air conditions was developed. The protocol features low-cost, environmentally benign solvent, mild reaction conditions and wide broad substrate scope.

Key words: water, green organic synthesis, sulfonamides, sulfonyl chlorides, iron power

Cite this article

Yue Huilan, Bao Pengli, Wang Leilei, Lü Xiaoxia, Yang Daoshan, Wang Hua, Wei Wei. Direct Synthesis Sulfonamides from Nitroarenes and Sulfonyl Chlorides in Water[J]. Chin. J. Org. Chem., 2019, 39(2): 463-468.

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通过硝基苯与磺酰氯水相反应直接合成磺酰胺

Direct Synthesis Sulfonamides from Nitroarenes and Sulfonyl Chlorides in Water

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