Recent Progress in Transition Metal Catalyzed Sulfonamidation of Aromatic Compounds

doi:10.6023/cjoc201910002

Abstract

The N-arylsulfonamide group is an important moiety in medicinal chemistry because of its presence in many useful molecules with potential bioactivities. As a result, the development of synthetic routes to N-arylsulfonamides has been actively investigated. In recent years, the transition metal-catalyzed sulfonamidations of aryl halides, arylboronic acids and C_Ar-H bonds have extensively investigated, providing more efficient and environmentally friendly procedures for the synthesis of N-arylsulfonamides. The recent progress in the transition metal-catalyzed sulfonamidation reactions is reviewed. The aromatic substrates, transition metal-catalysts, ligands, sulfonamidating reagents, mechanisms of the sulfonamidation reactions are mainly discussed. Finally, the future development of them is also prospected.

Key words: N-arylsulfonamides, sulfonamidation, transition metal-catalyzed, C-N bond construction, C-H bond activation

Cite this article

Ouyang Banlai, Zheng Yanxia, Xia Kejian, Xu Xiaoling, Wang Yi. Recent Progress in Transition Metal Catalyzed Sulfonamidation of Aromatic Compounds[J]. Chinese Journal of Organic Chemistry, 2020, 40(5): 1188-1205.

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