Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (9): 2678-2691.DOI: 10.6023/cjoc202002033 Previous Articles     Next Articles

醌亚胺单缩酮的合成以及应用研究进展

刘腾   

  1. 曲靖师范学院化学与环境科学学院 云南曲靖 655011
  • 收稿日期:2020-02-25 修回日期:2020-04-22 发布日期:2020-06-10
  • 通讯作者: 刘腾 E-mail:15288404381@163.com
  • 基金资助:
    云南省应用基础研究面上(No.2018FB019)、云南大学自然资源药物化学教育部重点实验室开放课题和大学生创新训练(Nos.201910684008,201910684027)资助项目.

Recent Progress on Quinone Imine Ketals: Synthesis and Applications

Liu Teng   

  1. College of Chemistry and Environmental Science, Qujing Normal University, Qujing, Yunnan 655011
  • Received:2020-02-25 Revised:2020-04-22 Published:2020-06-10
  • Supported by:
    Project supported by the Program for the Application Fundamental Research of Yunnan Province (No. 2018FB019), the Opening Foundation of Key Laboratory of Natural Resources Pharmaceutical Chemistry, Ministry of Education, Yunnan University and the Innovative Training Program for College Students (Nos. 201910684008, 201910684027).

In recent years, quinone imine ketals (QIKs) have been used as excellent organic synthons to the construction of complex organic molecules due to containing diverse functional groups (C=N, C=C and ketal etc.). Exploring the site-selectivity (chemo-, regio- and stereo-selectivity) of QIKs is not only a very significant research topic, but also a challenging research work. The preparation methods of QIKs and its applications in organic synthesis are reviewed according to the recent progress.

Key words: quinone imine ketal, organic synthon, chemoselectivity, regioselectivity, stereoselectivity