N—H Bond Activation of Ammonia by Transition Metal and Main Group Element Complexes

doi:10.6023/cjoc201301081

Abstract

Activation of ammonia has received increasing attention in recent years due to its important role both in nature and industry processes. A series of transition metal (such as Ir, Rh, Ru, Fe, Pd, etc.) and main group element (such as Si, Ge, Sn, etc.) complexes have been reported to activate N—H bond of ammonia in the past three decades. This review includes the recent progresses in homogeneous N—H bond activation of ammonia by transition metal and main group element complexes.

Key words: Ammonia, N—H bond, activation , transition metal complex, main group element complex

Cite this article

Fang Huayi, Ling Zhen, Fu Xuefeng. N—H Bond Activation of Ammonia by Transition Metal and Main Group Element Complexes[J]. Chin. J. Org. Chem., 2013, 33(04): 738-748.

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过渡金属及主族元素配合物活化NH₃中N—H键的研究进展