Chinese Journal of Organic Chemistry 2025, 45(1)

- About the Cover:
  
  The recent progress in the synthesis of α-tertiary amines via radical strategies is reviewed by Fang, Tian, Chen and Liu on page 22. Given the importance of α-tertiary amines and the advantages of radical reactions, various methods have been developed, including radical amina-tion/hydroamination of alkenes, radical C—N cross- coupling, radical addition of imines, and C—H bond activation of alkanes.
- About the Cover:
  
  In recent years, f-block metal arene complexes with various structural features have been synthesized and characterized by Deng, Wang and Huang on page 56. Particularly, low-valent f-block metals can form δ- symmetry interactions with arenes, enabling the access of unusual oxidation states and unprecedented redox chemistry. This review surveys the recent advancement of f-block metal-arene interactions and provides an outlook on the future development.
- About the Cover:
  
  The synthesis of novel near-infrared aggregation-indu- ced emission (AIE) molecules 1～3 by coupling two tri- arylamine-modified benzothiadiazole donnor-acceptor (D-A) units is reported by Dong, Su, Pan, Ren and Chen on page 205. In THF/H2O mixed solvents, the com-pounds 1～3 exhibited AIE properties with emission bands between 600～1000 nm and fluorescence quantum yields up to 13%.
- About the Cover:
  
  As typical poly-fluorinated molecules, the α-trifluoro- methyl ketones are stable and useful compounds in or-ganic synthesis. For the sake of displaying the value of these compounds, the research advances on the synthesis of α-trifluoromethyl ketones, as well as the defluorina-tion-based synthetic application of these compounds for the synthesis of diverse other organic products are re-viewed by Cao, Liu and Wan on page 86.
2025, 45(1)

25 January 2025
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REVIEWS ARTICLES NOTES HIGHLIGHTS

REVIEWS

Progress in [4＋1] Cycloadditions of Conjugated Dienes

Yefei Zhang, Yong Tang, You-Yun Zhou

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 1-21 DOI: 10.6023/cjoc202407043

Abstract( 600) HTML( 27) PDF(1271KB)( 590 )

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Research Progress in the Synthesis of α-Tertiary Amines via Radical Strategies

Jiaheng Fang, Runyan Tian, Jijun Chen, Xinyuan Liu

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 22-41 DOI: 10.6023/cjoc202406040

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Research Progress in Benzene-Forming Cyclotrimerization Reactions

Cen Zhou, Xin Zhao, Xiao Zhang

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 42-55 DOI: 10.6023/cjoc202407048

Abstract( 438) HTML( 11) PDF(687KB)( 289 )

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f-Block Metal-Arene Interactions

Chong Deng, Yi Wang, Wenliang Huang

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 56-85 DOI: 10.6023/cjoc202405017

Abstract( 557) HTML( 17) PDF(1947KB)( 866 )

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Advances in the Synthesis of α-Trifluoromethyl Ketones and Their Application via Defluorinative Reactions

Sufang Cao, Yunyun Liu, Jieping Wan

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 86-103 DOI: 10.6023/cjoc202411018

Abstract( 429) HTML( 91) PDF(684KB)( 925 )

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Research Progress on Carbonylation Involving Name Reactions

Yaowei Wang, Peng Wang, Huibing Shi, Chengfu Zhang, Deming Zhao, Guiai Yang, Yaozong Yan, Baolin Feng

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 104-135 DOI: 10.6023/cjoc202406043

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Application of Hydrophobic Catalysts in Organic Synthesis Reactions

Jing Xu, Juan Zhang, Wenchao Gao, Fanhui Meng, Peng Yang, Honghong Chang

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 136-150 DOI: 10.6023/cjoc202406019

Abstract( 349) HTML( 6) PDF(4813KB)( 381 )

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Research Progress on Transition Metal Catalyzed Hydrocarbonation Reactions of N-Allenamines

Junwei Wang, Hao Xue, Yingyu Qu, Ruonan Jiang, Fachao Yan, Hui Liu

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 151-167 DOI: 10.6023/cjoc202406007

Abstract( 304) HTML( 5) PDF(1337KB)( 230 )

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Progress in Functionalization of N-α-C_sp3—H Bond Catalyzed by Transition Metals

Tengfei Zhang, Zhe Chang, Chunxia Chen, Jinsong Peng

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 168-188 DOI: 10.6023/cjoc202404040

Abstract( 384) HTML( 29) PDF(1160KB)( 632 )

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ARTICLES

α-Thiocyanation of Enol Acetates and Sodium Thiocyanate under Electrochemical Conditions

Jinpeng Zhang, Yuliang Qian, Mengyan Ning, Tongqin Cai, Jingyao Su-Zhang, Quan Yu, Liangce Rong

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 189-195 DOI: 10.6023/cjoc202410007

Abstract( 249) HTML( 10) PDF(544KB)( 158 )

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Design, Synthesis and Bioactivity of Novel 2-Phenylethanol Ester Derivatives Containing Monoterpene Fragments

Shixiang Pan, Yan Liu, Zhuo Shi, Xingxing Lu, Yaoguo Qin, Cheng Qu, Chen Chen, Xinling Yang

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 196-204 DOI: 10.6023/cjoc202407021

Abstract( 276) HTML( 13) PDF(4139KB)( 515 )

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Near-Infrared Aggregation-Induced Emission (AIE) Molecules Based on Coupling of Triarylamine-Modified Benzothiadiazole Units

Zixuan Dong, Junjun Su, Hongfei Pan, Xiangkui Ren, Zhijian Chen

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 205-211 DOI: 10.6023/cjoc202407014

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Application of Triborylmethane Reagent in the Stereoselective Synthesis of Dissymmetric gem-Diborylalkenes

Tiantian Yang, Du Chen, Peng Zhang, Chao Liu

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 212-219 DOI: 10.6023/cjoc202406008

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Process Development and Scale-Up of (S)-tert-Butyl(6-oxopiperdin-3-yl)carbamate

Yongsheng Li, Xiaowen Tang, Xu Li, Peng Yang

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 220-226 DOI: 10.6023/cjoc202406006

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Design, Synthesis and Insecticidal Activity of New Phenylpyrazole Derivatives

Haiping Tian, Dongdong Liu, Hongyan Pei, Jialin Ye, Zirui Zheng, Yixing Gao, Changxing Li, Huan Tian, Jing Zhang, Lixin Zhang

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 227-239 DOI: 10.6023/cjoc202405024

Abstract( 266) HTML( 10) PDF(3079KB)( 385 )

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Synthesis of Thioureas from Amines and CS₂ via Photoredox Catalysis

Wei Li, Yisen Wang, Rong Zhou, Wenchao Gao

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 240-245 DOI: 10.6023/cjoc202405007

Abstract( 365) HTML( 21) PDF(1653KB)( 282 )

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Functionalized Ionic Liquid [BMim]OH-Catalyzed the Synthesis of β-Ketosulfones and Sulfone Compounds between α-Halides and Sodium Sulfinate

Haoyang Wang, Lin Cheng, Xing Zeng, Limin Han, Yuying Du, Ning Zhu

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 246-255 DOI: 10.6023/cjoc202406010

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Synthesis of Difluorocyclopropanes via a Photoinduced [1＋2] Cycloaddition of Diazo Esters with gem-Difluoroalkenes

Xiaonan Mu, Minhui Guan, Yulong Niu, Hao Chen, Chuanying Li, Lei Wang

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 256-266 DOI: 10.6023/cjoc202406027

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N-Heterocyclic Carbene-Catalyzed [4＋2] Cycloaddition of Salicylaldehydes with Pyrazole-4,5-diones for the Synthesis of Spiroketal-Pyrazolones

Xiaomei Wang, Yan Liu, Shiwu Li, Zhifei Zhao

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 267-275 DOI: 10.6023/cjoc202406005

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Design, Synthesis and Bioactivity Research of Novel Bipyridine Compounds

Xingxing Lu, Yufan Lin, Huan Xu, Xiaoming Zhang, Xuesheng Li, Yun Ling, Xinling Yang

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 276-285 DOI: 10.6023/cjoc202405010

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Synthesis and Anti-acute Myeloid Leukemia Activity of Cyclopropane-1,1-diamide Derivatives Containing Imidazo[1,2-a]pyridine

Lüjia Wu, Jiangdong Li, Zhonghua Shi, Xin Jin, Xianheng Wang, Changkuo Zhao, Qiang Huang

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 286-296 DOI: 10.6023/cjoc202403053

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Cu-Catalyzed Regioselective Heteroarylation of C(sp³)—H Bond Induce by Sulfonyl Group

Huiying Liu, Zhongtian Wu, Haotian Li, Xinxin Wu

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 297-306 DOI: 10.6023/cjoc202406034

Abstract( 352) HTML( 33) PDF(600KB)( 347 )

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Copper(I)-Catalyzed Acylation/Cyclization of 2-Aryl-N-acryloyl Indole toward Indolo[2,1-α]isoquinoline Derivatives

Mengna Yang, Yucai Tang, Jie Jiang, Jiali Li, Ruohan Pan, Yu Chen, Jinglin Duan, Songbai Zhang

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 307-318 DOI: 10.6023/cjoc202405027

Abstract( 253) HTML( 5) PDF(630KB)( 194 )

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Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties

Jianfa Li, An Duan, Xiaoyu Huang, Yongjun Li

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 319-324 DOI: 10.6023/cjoc202407011

Abstract( 250) HTML( 4) PDF(664KB)( 231 )

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Impact of the Molecular Weight of Poly(vinyl dimethylphenazine) on Its Electrochemical Behavior

Ziheng Wang, An Duan, Xiaoyu Huang, Yongjun Li

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 325-330 DOI: 10.6023/cjoc202406004

Abstract( 163) HTML( 8) PDF(2234KB)( 211 )

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Rhodium(III)-Catalyzed Annulative Coupling between Sulfoxonium Ylides and Diazo Compounds

Fan Yang, Xiaomeng Fan, Xuejing Yao, Ruijie Mi, Songjie Yu, Xingwei Li, Jian Xiao

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 331-342 DOI: 10.6023/cjoc202405011

Abstract( 295) HTML( 8) PDF(614KB)( 365 )

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Total Syntheses of Cochlearol F and Didehydroconicol by Biphenyl Boronic Acid

Kai Wang, Jiajun Sui, Chunhong Long, Songjuan Luo, Yongming Chuan, Hongbo Qin

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 343-348 DOI: 10.6023/cjoc202404042

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Selective Synthesis of 3-Selenoindoles via Selenation of Indoles under Catalyst-Free Condition

Dengpeng Xia, Qi Wu, Zhihua Cai, Guangfen Du

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 349-357 DOI: 10.6023/cjoc202404031

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NOTES

Synthesis and Herbicidal Activity of Di-substituted Pyrimidine-Biphenyls and Study of Molecular Mode of Action

Yitao Yan, Yinglu Chen, Hanxian Hu, Jun Wu

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 358-366 DOI: 10.6023/cjoc202405035

Abstract( 260) HTML( 6) PDF(1694KB)( 187 )

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HIGHLIGHTS

Lewis Acid Catalyzed (3＋3) Cyclization Reaction of Bicyclobutanes Promoted by Cross-Exchange-Based Ring Expansion

Jian Zhang, Weiping Deng

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 367-369 DOI: 10.6023/cjoc202500001

Abstract( 210) HTML( 7) PDF(527KB)( 158 )

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Iterative Hydrosilanes Synthesis via Borane-Catalyzed Intermolecular Aryl Transfer between Hydrosilanes

Xianzhou Zheng, Weiming Yuan

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 370-373 DOI: 10.6023/cjoc202500002

Abstract( 133) HTML( 8) PDF(419KB)( 79 )

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Phosphine-Catalyzed Asymmetric Synthesis of Chiral 2-Azetines and Axially Chiral Tetrasubstituted Allenes

Dongqiu Li, Silong Xu

Chinese Journal of Organic Chemistry 2025, 45 (1), pp 374-375 DOI: 10.6023/cjoc202500003

Abstract( 155) HTML( 6) PDF(401KB)( 111 )

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