Research Progress of C-H bond Asymmetric Hydroxylation

doi:10.6023/cjoc202412014

Abstract

Chiral alcohol derivatives are an important class of molecules that exist in many bioactive substances and natural products, and are also an important class of organic synthetic intermediates used to synthesize many important organic compounds. Biomimetic catalysis has been emerging as a very powerful tool for catalytic asymmetric hydroxylation after biocatalysis, and this type of reaction is mainly innovative in the design of novel ligands and their application in asymmetric catalytic reactions. Therefore, it is of great significance to develop efficient, green and highly chemical and steroselective methods for the synthesis of chiral alcohols. In this paper, we summarize the asymmetric hydroxylation of C-H bonds over the past two decades, and classify and summarize such reactions according to the types of catalysts, which are mainly divided into two categories: biocatalysis and biomimetic catalysis.

Key words: asymmetric hydroxylation, enantioselectivity, enzymatic catalysis, biomimetic catalysis, chiral ligands

Cite this article

Wu Ye, Chen Chunxia, Peng Jinsong. Research Progress of C-H bond Asymmetric Hydroxylation[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202412014.

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