Study on synthesis and catalysis of mixed-metal clusters iii.  Synthesis of Pt(P(C6H5)3)2Cl2 from K2PtCl6

Abstract

This paper describes a new method of synthesizing platinum complex Pt(P(C6H5)3)2Cl2 from K2PtCl6 and P(C6H5)3 directly. The product have been identified by elemental analysis, physical constants determination, IR and mass spectra. By isolation and identification of the by-product (C6H5)3PO, it is shown that triphenylphosphine acts as the ligand and also the reducing agent in the reaction.

Key words: OXIDATION, CHLORO COMPLEX, POTASSIUM COMPOUNDS, ORGANO TRANSITION METAL COMPOUNDS, PLATINUM COMPLEX, CLUSTER COMPOUND, TRIPHENYL GROUP, TRIPHENYL GROUP, PLATINATE

CLC Number:

O627

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ZHAI WEIXU;LI DAGANG. Study on synthesis and catalysis of mixed-metal clusters iii. Synthesis of Pt(P(C6H5)3)2Cl2 from K2PtCl6[J]. Chin. J. Org. Chem., 1983, 3(4): 263-266.

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异核金属簇合成及催化作用的研究III.从铂(IV)合成铂(II)的络合物Pt[P(C6H5)3]Cl2*

Study on synthesis and catalysis of mixed-metal clusters iii. Synthesis of Pt(P(C6H5)3)2Cl2 from K2PtCl6

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