The stereoselectivity of some pinacol reaction with CpTiCl3-LiAlH4 as the reductive coupling agent

Chin. J. Org. Chem. ›› 1988, Vol. 8 ›› Issue (2): 134-138. Previous Articles Next Articles

用^1H NMR法研究以CpTiCl3-LiAlH4为还原剂的pinacol反应的立体选择性

刘兴平;潘鑫复;李裕林;梁晓天

兰州大学有机化学研究所;中国医学科学院药物研究所

发布日期:1988-04-25

The stereoselectivity of some pinacol reaction with CpTiCl3-LiAlH4 as the reductive coupling agent

LIU XINGPING;PAN XINFU;LI YULIN;LIANG XIAOTIAN

Published:1988-04-25

Abstract

The 1H NMR spectra of cyclic carbonates and acetals of secondary-secondary glycolic systems can be used to estimate the ratio of erythro and threo isomers. The pinacols from four groups of achiral aldehydes with CpTiCl3-LiAlH4 as the reductive coupling agent were examined The threo isomers were found to be the major products.

Key words: CHLORIDE, CYCLOPENTADIENE, PROTON MAGNETIC RESONANCE SPECTROMETRY, STEREOSELECTIVITY, ALDEHYDES, TITANIUM COMPLEX, REDUCER, ACETAL, PINACOL REARRANGEMENT, POLYCARBONATE, LITHIUM ALUMINIUM HYDRIDE

CLC Number:

O621.16
O267

Cite this article

LIU XINGPING;PAN XINFU;LI YULIN;LIANG XIAOTIAN. The stereoselectivity of some pinacol reaction with CpTiCl3-LiAlH4 as the reductive coupling agent[J]. Chin. J. Org. Chem., 1988, 8(2): 134-138.

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用^1H NMR法研究以CpTiCl3-LiAlH4为还原剂的pinacol反应的立体选择性

The stereoselectivity of some pinacol reaction with CpTiCl3-LiAlH4 as the reductive coupling agent

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