Synthesis of water soluble quaternary ammonium pyridine prophyrins and their metal complexes

Chin. J. Org. Chem. ›› 1990, Vol. 10 ›› Issue (1): 50-54. Previous Articles Next Articles

Original Articles

几种氰类, 酯类取代基季铵盐吡啶卟啉及其金属配合物的合成

吴萱阶;周翔;陈彭平

武汉大学化学系

发布日期:1990-02-25

Synthesis of water soluble quaternary ammonium pyridine prophyrins and their metal complexes

WU XUANJIE;ZHOU XIANG;CHEN PENGPING

Published:1990-02-25

Abstract

I (R = CH2CN, CH2CH2CN, CH2CO2Et, CH2CO2Me, CHMeCO2Et) were prepared from tetrakis(4-pyridyl)porphyrin and XR (X = Cl or Br). CoL(ClO4)4(OAc) (H2L = I) and MLX4 (M = Cu, Ni, Zn; X = ClO4, Br, Cl) were prepared and characterized by IR, NMR and ESR (Cu complexes) spectra.

Key words: PORPHINE P, PORPHINE P, PYRIDINE P, INFRARED SPECTROPHOTOMETRY, WATER SOLUBILITY, HALIDE, ESTERS, ORGANIC SYNTHESIS, NMR SPECTROMETRY, PYRIDINE

CLC Number:

O627

Cite this article

WU XUANJIE;ZHOU XIANG;CHEN PENGPING. Synthesis of water soluble quaternary ammonium pyridine prophyrins and their metal complexes[J]. Chin. J. Org. Chem., 1990, 10(1): 50-54.

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几种氰类, 酯类取代基季铵盐吡啶卟啉及其金属配合物的合成

Synthesis of water soluble quaternary ammonium pyridine prophyrins and their metal complexes

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