Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (4): 1215-1240.DOI: 10.6023/cjoc202207013 Previous Articles     Next Articles



莫百川a,b, 陈春霞a,b,*(), 彭进松a,*()   

  1. a 东北林业大学化学化工与资源利用学院 哈尔滨 150040
    b 东北林业大学材料科学与工程学院 哈尔滨 150040
  • 收稿日期:2022-08-19 修回日期:2022-09-21 发布日期:2022-11-15
  • 通讯作者: 陈春霞, 彭进松
  • 基金资助:
    中央高校基本科研业务费专项(2572020AW45); 黑龙江省自然科学基金(ZD2021C001); 高等学校学科创新引智计划(B20088)

Research Progress in Application of Lignin and Its Derivatives Supported Metal Catalysts in Organic Synthesis

Baichuan Moa,b, Chunxia Chena,b(), Jinsong Penga()   

  1. a College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040
    b Material Science and Engineering College, Northeast Forestry University, Harbin 150040
  • Received:2022-08-19 Revised:2022-09-21 Published:2022-11-15
  • Contact: Chunxia Chen, Jinsong Peng
  • Supported by:
    Fundamental Research Funds for the Central Universities(2572020AW45); Natural Science Foundation of Heilongjiang Province(ZD2021C001); Program of Introducing Talents of Discipline to Universities(B20088)

The attention of biomass-based catalysts has been continuously increased due to the proposal of carbon neutralization development concept. The use of lignin as a support for transition metal catalysts for the preparation of heterogeneous catalysts in the field of organic synthesis can greatly improve the utilization value of lignin. The extensive presence of oxygen-containing functionalities in the lignin structure provides a variety of binding sites for the loading of metal catalysts, and metal particles can be efficiently captured by physical adsorption/deposition, ion exchange, and electrostatic complexation with hydroxyl functional groups. The structure of lignin is firstly introduced, and the methods for preparing heterogeneous catalysts are then described. Lignin and its derivatives supported metal catalysts catalyzed Click reaction, Glaser reaction, Huisgen [3+2] cycloaddition reaction, Heck reaction, Suzuki reaction, Sonogashira reaction, Stille coupling, Michael addition/dehydration tandem, Electrophilic ring-opening reaction, Fridel-Crafts type reaction, ethylene polymerization and other reactions. Thus, at the end of this review, the existing problems and development trends are prospected.

Key words: functionalized lignin, lignin-supported metal catalyst, heterogeneous catalysis, organic synthesis, green chemistry