Decomposingly coupled reaction of 3, 5-di-t-butylcatechol with hydrogenperoxide

Chin. J. Org. Chem. ›› 1996, Vol. 16 ›› Issue (2): 182-185. Previous Articles Next Articles

Original Articles

3, 5-二叔丁基邻苯二酚的过氧化降解偶合反应研究

杨日芳;赵毅民;李光玉;恽榴红

军事医学科学院毒物药物研究所

发布日期:1996-04-25

Decomposingly coupled reaction of 3, 5-di-t-butylcatechol with hydrogenperoxide

YANG RIFANG;ZHAO YIMIN;LI GUANGYU;YUN LIUHONG

Published:1996-04-25

Abstract

Oxidation of 3, 5-di-t-butylpyrocatechol with hydrogen peroxide to prepare 3, 5-di-t-butyl-o-quinone produced 3, 5-di-t-butyl-5-(2, 4-di- t-butyl-6-hydroxy phenoxy)-2-furanone (2) unexpectedly, A decomposition couping mechanism is suggested.

Key words: DEGRADATION REACTION, REACTION MECHANISM, BENZOQUINONE P, COUPLING REACTION, INFRARED SPECTROPHOTOMETRY, NMR SPECTROMETRY, BENZENEDIOL P, MASS SPECTROGRAPHY, FURANONE P

CLC Number:

O621

Cite this article

YANG RIFANG;ZHAO YIMIN;LI GUANGYU;YUN LIUHONG. Decomposingly coupled reaction of 3, 5-di-t-butylcatechol with hydrogenperoxide[J]. Chin. J. Org. Chem., 1996, 16(2): 182-185.

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3, 5-二叔丁基邻苯二酚的过氧化降解偶合反应研究

Decomposingly coupled reaction of 3, 5-di-t-butylcatechol with hydrogenperoxide

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