Application of Electroauxiliaries in Electroorganic Synthesis

Abstract

This review is about the application of electroauxiliaries in electroorganic synthesis in recent years. The electroauxiliaries have two types. One is the organic group which contains silicon, tin, germanium and other element of IVA group, the other contains organothio group. The electroauxiliaries raised the energy of HOMO, accelerated the transfer of electron, and lowered the oxidation potential of the substrate. This enabled the rupture of special bond and combined with the desired nucleophile, reducing the chance for overoxidation and enhancing the selectivity of the reaction. The electroauxiliaries will be widely used in electroorganic synthesis.

Key words: electroauxiliariy, ELECTROSYNTHESIS, APPLICATION

CLC Number:

O621

Cite this article

Zhao Ping;Yin Yingwu. Application of Electroauxiliaries in Electroorganic Synthesis[J]. Chin. J. Org. Chem., 2003, 23(7): 628-635.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Chunyan She, Anjing Wang, Shan Liu, Wenming Shu, Weichu Yu. Preparation of Phenacyl Azides and Their Application Advances in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 481-507.
[2]	Shutong Zhou, Shengnan Tu, Zijian Gao, Yemei Wang, Shasha Sun. Research Progress in Synthesis, Properties and Application of Subphthalocyanine [J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2628-2646.
[3]	Guangli Xu, Jing Xu, Haidong Xu, Xiang Cui, Xingzhong Shu. Research Progress of Transition Metal Catalyzed Synthesis of 1,3- Conjugated Diene Compounds from Alkenes and Alkynes [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 1899-1933.
[4]	Liangru Yang, Mengli Guo, Jinwei Yuan, Jiamei Wangx, Yuting Xia, Yongmei Xiao, Pu Mao. Research Progress on Pincer N-Heterocyclic Carbene Metal Complexes [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 2002-2025.
[5]	Yangyang Li, Xiaofei Sun, Xiaoling Hu, Yuanyuan Ren, Keli Zhong, Xiaomei Yan, Lijun Tang. Synthesis of Triphenylamine Derivative and Its Recognition for Hg²⁺ with “OFF-ON” Fluorescence Response Based on Aggregation-Induced Emission (AIE) Mechanism [J]. Chinese Journal of Organic Chemistry, 2023, 43(1): 320-325.
[6]	Lixin Ju, Qi Shao, Linchuan Lu, Hongfei Lu. A New Turn-On Fluorescent Chemosensor for Selective Detection of Al³⁺ Based on a Purine Schiff Base and Its Cell Imaging [J]. Chinese Journal of Organic Chemistry, 2022, 42(6): 1706-1712.
[7]	Sihong Chen, Jiamin Xu, Yuemei Li, Baoru Peng, Lingyu Luo, Huiye Feng, Zhaohua Chen, Zhaoyang Wang. Research Progress of Aggregation-Caused Quenching (ACQ) to Aggregation-Induced Emission (AIE) Transformation Based on Organic Small Molecules [J]. Chinese Journal of Organic Chemistry, 2022, 42(6): 1651-1666.
[8]	Zhaoxin Wei, Renjie Wang, Yonghong Zhang, Bin Wang, Yu Xia, Weiwei Jin, Chenjiang Liu. Electrochemical Synthesis of N-Acyl/Sulfonylsulfenamides Using Potassium Iodide as Mediator [J]. Chinese Journal of Organic Chemistry, 2022, 42(11): 3730-3739.
[9]	Wei Meng, Kun Xu, Bingbing Guo, Chengchu Zeng. Recent Advances in Minisci Reactions under Electrochemical Conditions [J]. Chinese Journal of Organic Chemistry, 2021, 41(7): 2621-2635.
[10]	Muxue He, Shiyan Cheng, Yongzhou Pan, Haitao Tang, Yingming Pan. Electrochemically Mediated S—N Bond Formation: Synthesis of Sulfenamides [J]. Chinese Journal of Organic Chemistry, 2021, 41(6): 2354-2360.
[11]	Sihong Chen, Qi Chen, Shihe Luo, Xiying Cao, Guoxian Yang, Xiaoqing Zeng, Zhaoyang Wang. Progress in Design, Synthesis and Application of Triphenylamine-Based Fluorescent Probes [J]. Chinese Journal of Organic Chemistry, 2021, 41(3): 919-933.
[12]	Shiyan Cheng, Chuhong Ou, Hongmin Lin, Junsong Jia, Haitao Tang, Yingming Pan, Guobao Huang, Xiujin Meng. Electrochemically Mediated Esterification of Aromatic Aldehydes with Aliphatic Alcohols via Anodic Oxidation [J]. Chinese Journal of Organic Chemistry, 2021, 41(12): 4718-4724.
[13]	Hehua Xu, Xiangtai Meng, Yu Zheng, Jinyue Luo, Shenlin Huang. Electrochemical Annulations of o-Alkynylanilines for Synthesis of 3-Iodoindoles [J]. Chinese Journal of Organic Chemistry, 2021, 41(12): 4696-4703.
[14]	Chaohui Cui, Yuting Liu, Ya Du. Recent Advancements of Hexaazatriphenylene-Based Materials for Energy Applications [J]. Chinese Journal of Organic Chemistry, 2021, 41(11): 4167-4179.
[15]	Han Ren, Ruxiang Li, Zhijian Chen, Lili Li, Hao Wang. Modification Methods and Applications of Self-Assembly Peptides [J]. Chinese Journal of Organic Chemistry, 2021, 41(10): 3983-3994.

电辅基在有机电合成中的应用