Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (12): 1559-1562. Previous Articles     Next Articles

金属卟啉配合物催化3β-取代的Δ5-甾体衍生物立体选择性环氧化及酰胺化反应研究

李玫, 赵元聪, 孙利, 程化, 余孝其*, 谢如刚*   

  1. 四川大学化学学院 绿色化学与技术教育部重点实验室 成都 610064
  • 收稿日期:2004-02-16 修回日期:2004-04-08 接受日期:2004-06-01 发布日期:2022-09-20

Diastereoselective Epoxidation and Amidation of 3β-Substituted Δ5-Steroid Derivatives Catalyzed by Manganese and Ruthenium Porphyrins

LI Mei, ZHAO Yuan-Cong, SUN Li, CHENG Hua, YU Xiao-Qi*, XIE Ru-Gang*   

  1. Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064
  • Received:2004-02-16 Revised:2004-04-08 Accepted:2004-06-01 Published:2022-09-20
  • Contact: *E-mail: panxf@lzu.edu.cn

(meso-Tetrakis(2,6-dichlorophenyl)porphyrin)manganese chloride and carbonyl ruthenium meso-tetrakis(2,6-dichlorophenyl)porphyrin were prepared and used to catalyze the diastereoselective epoxidation and amidation of 3β-substituted Δ5-steroid derivatives.

Key words: metalloporphyrin, steroid, diastereoselectivity, epoxidation, amidation