Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (7): 825-827. Previous Articles     Next Articles

微波促进Ni(II)催化下烷基锌与芳香醛的烯基化反应

门秀琴, 王克虎, 王进贤*, 施小宁   

  1. 西北师范大学化学化工学院 兰州 730070
  • 收稿日期:2003-11-03 修回日期:2003-12-16 接受日期:2004-01-21 发布日期:2022-09-20
  • 通讯作者: *E-mail: wangjx@nwnu.edu.cn
  • 基金资助:
    国家自然科学基金(No. 20272047)、甘肃省高分子材料重点实验室基金、西北师范大学科技创新工程(No. 01-04)资助项目

Microwave Assisted Nickel(II) Catalyzed Stereoselective Olefination of Aryl Aldehydes with Alkylzinc Reagents

MEN, Xiu-Qin, WANG, Ke-Hu, WANG, Jin-Xian*, SHI, Xiao-Ning   

  1. College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070
  • Received:2003-11-03 Revised:2003-12-16 Accepted:2004-01-21 Published:2022-09-20

Functionalized alkylzinc reacted with aryl aldehydes in the presence of Me3SiCl using a nickel(II) complex as catalyst under microwave irradiation to give E-olefins in high yield. The reaction time was shortened 90~120 times.

Key words: microwave irradiation, olefination, alkylzinc, aldehyde