Chin. J. Org. Chem. ›› 2005, Vol. 25 ›› Issue (07): 869-871. Previous Articles    

Reports

Eu(NTf2)3催化吲哚与醛(酮)反应合成二吲哚基甲烷

王宏社*,赵立芳   

  1. (宝鸡文理学院化学化工系 宝鸡721007)
  • 收稿日期:2004-08-31 修回日期:2005-01-29 发布日期:2005-06-30
  • 通讯作者: 王宏社

Efficient Europium Bis(trifluoromethanesulfonyl)amide Catalyzed Synthesis of Bis(indol-3-yl)methanes

WANG Hong-She*,ZHAO Li-Fang   

  1. (Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721007)
  • Received:2004-08-31 Revised:2005-01-29 Published:2005-06-30
  • Contact: WANG Hong-She

Europium bis(trifluoromethanesulfonyl)amide, Eu(NTf2)3 (Tf=SO2CF3), was found to catalyze efficiently the electrophilic substitution reactions of indoles with aldehydes or ketones to afford the corresponding bis(indol-3-yl)methanes in high yields at room temperature. Eu(NTf2)3 could be reused.

Key words: bis(indol-3-yl)methane, aldehyde, Eu(NTf2)3, ketone, indole