Chin. J. Org. Chem. ›› 2005, Vol. 25 ›› Issue (9): 1039-1044. Previous Articles     Next Articles

Review

聚合物支载噁唑类化合物在不对称反应中的应用

万亚东,陈祖兴*,杨桂春   

  1. (湖北大学化学与材料科学学院 武汉 430062)
  • 收稿日期:2004-09-06 修回日期:2005-02-28 发布日期:2005-08-24
  • 通讯作者: 陈祖兴

Application of Polymer-supported Oxazo-type Compounds to Asymmetric Reactions

WAN Ya-Dong,CHEN Zu-Xing*,YANG Gui-Chun   

  1. (Faculty of Chemistry and Material, Hubei University, Wuhan 430062)
  • Received:2004-09-06 Revised:2005-02-28 Published:2005-08-24
  • Contact: CHEN Zu-Xing

Oxazo-type compounds mainly include oxazolidinone, oxazoline and oxazaborolidine. Usually they are used as chiral auxiliaries, chiral catalysts and chiral ligands in asymmetric reactions. They were widely used in asymmetric reactions due to the advantages of easy isolation and circular use with no apparent reduction of stereoselectivity. The general applications of polymer-supported oxazo-type compounds to asymmetric reactions were reviewed.

Key words: asymmetric reaction, oxazolidinone, oxazaborolidine, oxazoline, polymer supported