Cerium(III) Chloride Promoted Reactions and Their Applications to Organic Synthesis

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Chin. J. Org. Chem. ›› 2005, Vol. 25 ›› Issue (9): 1029-1038. Previous Articles Next Articles

Review

三氯化铈促进的反应及其在有机合成中的应用

范学森*^,1，李艳贞¹，张永敏²,3

(¹河南师范大学化学与环境科学学院新乡 453007)
(²浙江大学西溪校区化学系杭州 310028)
(³中国科学院上海有机化学研究所金属有机化学国家重点实验室上海 200032)

收稿日期:2004-10-25 修回日期:2005-02-28 发布日期:2005-08-24
通讯作者: 范学森

Cerium(III) Chloride Promoted Reactions and Their Applications to Organic Synthesis

FAN Xue-Sen*^,1,LI Yan-Zhen¹,ZHANG Yong-Min²,3

(¹School of Chemical and Environmental Sciences, Henan Normal University, Xinxiang 453007)
(²Department of Chemistry, Zhejiang University at Xixi Campus, Hangzhou 310028)
(³State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry,
Chinese Academy of Sciences, Shanghai 200032)

Received:2004-10-25 Revised:2005-02-28 Published:2005-08-24

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Abstract

Recent progress in cerium(III) chloride promoted organic reactions and their applications to organic synthesis were reviewed in this paper with the focus on carbon-carbon and carbon-heteroatom bonds formation reactions and selective deprotection reactions.

Key words: organic reaction, organic synthesis, Lewis acid, cerium(III) chloride

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FAN Xue-Sen*^,1,LI Yan-Zhen,ZHANG Yong-Min^2,3. Cerium(III) Chloride Promoted Reactions and Their Applications to Organic Synthesis[J]. Chin. J. Org. Chem., 2005, 25(9): 1029-1038.

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[1]	Luyao Li, Zhongwen He, Zhenguo Zhang, Zhenhua Jia, Teck-Peng Loh. Application of Triaryl Carbenium in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 421-437.
[2]	Qianfan Zhao, Yongzheng Chen, Shiming Zhang. Application and Mechanism Study of Carbon-Based Metal-Free Catalysts in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 137-147.
[3]	Zujia Chen, Shiwei Yu, Yongjun Zhou, Huanqing Li, Qiwen Qiu, Miaoxin Li, Zhaoyang Wang. Application of BF₃•OEt₂ in Organic Synthesis as a Catalyst or Synthon [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3107-3118.
[4]	Ran Zhou, Chunmei Yuan, Tao Zhang, Piao Mao, Yi Liu, Kaini Meng, Hui Xin, Wei Xue. Design, Synthesis and Bioactivity of Chalcone Derivative Containing Quinazolinone [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3196-3209.
[5]	Guangli Xu, Jing Xu, Haidong Xu, Xiang Cui, Xingzhong Shu. Research Progress of Transition Metal Catalyzed Synthesis of 1,3- Conjugated Diene Compounds from Alkenes and Alkynes [J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 1899-1933.
[6]	Qian Dou, Taimin Wang, Lijing Fang, Hongbin Zhai, Bin Cheng. Recent Development of Photoinduced Iron-Catalysis in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1386-1415.
[7]	Shiquan Gao, Chuangjun Liu, Junfeng Yang, Junliang Zhang. Cobalt-Catalyzed Electrochemical Reductive Coupling of Alkynes and Alkenes [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1559-1565.
[8]	Linsheng Bai, Peng Hong, Anguo Ying. Research Progress of Functional Polyacrylonitrile Fiber in Promoting Organic Reaction [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1241-1270.
[9]	Baichuan Mo, Chunxia Chen, Jinsong Peng. Research Progress in Application of Lignin and Its Derivatives Supported Metal Catalysts in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1215-1240.
[10]	Weidi Cao, Xiaohua Liu. Recent Advances on Catalytic Enantioselective Protonation for Construction of α-Tertiary Carbonyl Compounds [J]. Chinese Journal of Organic Chemistry, 2023, 43(3): 961-973.
[11]	Biao Ma, Miaomiao Zhang, Zhanyu Li, Jinsong Peng, Chunxia Chen. Recent Advance of Transition Metal-Free Catalyzed Suzuki-Type Cross Coupling Reaction [J]. Chinese Journal of Organic Chemistry, 2023, 43(2): 455-470.
[12]	Xiangqing Feng, Haifeng Du. B(C₆F₅)₃-Catalyzed Silylation of Unsaturated Hydrocarbons [J]. Chinese Journal of Organic Chemistry, 2023, 43(10): 3544-3557.
[13]	Yiling Zhao, Zhikang Chen, Lei Li, Conglei Liu, Hongping Zhu. Silylene/Organoaluminum Lewis Pair System and the Initiation Property for Polymerization of (Meth)acrylates [J]. Chinese Journal of Organic Chemistry, 2023, 43(10): 3590-3597.
[14]	Silin Chen, Yunhui Yang, Chao Chen, Congyang Wang. Advances in Transition-Metal-Catalyzed Keto Carbonyl-Directed C—H Bond Functionalization Reactions [J]. Chinese Journal of Organic Chemistry, 2023, 43(1): 1-16.
[15]	Dan Ba, Guolin Cheng. Blue Light Induced Insertion of Carbene into C(CO)—C Bonds of 1,3-Diones [J]. Chinese Journal of Organic Chemistry, 2022, 42(9): 2888-2897.