Ce2(SO4)3-Catalyzed Friedel-Crafts Alkylation of Aromatic Compounds with Benzyl Alcohols, Allyl Alcohols and Benzyl Chlorides

Chin. J. Org. Chem. ›› 2005, Vol. 25 ›› Issue (9): 1045-1048. Previous Articles Next Articles

Original Articles

硫酸亚铈催化的芳香化合物与苄基醇、烯丙醇类化合物以及苄基氯的傅-克烷基化反应研究

李金恒*，刘文杰，梁云，谢叶香

(湖南师范大学化学化工学院化学生物学与中药分析重点实验室长沙 410081)

收稿日期:2004-07-09 修回日期:2005-03-15 发布日期:2005-08-24
通讯作者: 李金恒

Ce₂(SO₄)₃-Catalyzed Friedel-Crafts Alkylation of Aromatic Compounds with Benzyl Alcohols, Allyl Alcohols and Benzyl Chlorides

LI Jin-Heng*,LIU Wen-Jie,LIANG Yun,XIE Ye-Xiang

(Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research, College of Chemistry and Chemical
Engineering, Hunan Normal University, Changsha 410081)

Received:2004-07-09 Revised:2005-03-15 Published:2005-08-24
Contact: LI Jin-Heng

Abstract

Ce₂(SO₄)₃ was used as an inexpensive and effective catalyst for the Friedel-Crafts alkylation of aromatic compounds with benzyl alcohols, allyl alcohols and benzyl chlorides. In the presence of 1～10 mol% of Ce₂(SO₄)₃, Friedel-Crafts alkylation reactions of aromatic compounds with benzyl alcohols, allyl alcohols and benzyl chlorides were carried out smoothly and efficiently. Moreover, the catalyst could be recovered and reused three times without significant loss of activity.

Key words: allyl alcohol, Friedel-Crafts alkylation, aromatic compound, benzyl chloride, benzyl alcohol, Ce₂(SO₄)₃

Cite this article

LI Jin-Heng*,LIU Wen-Jie,LIANG Yun,XIE Ye-Xiang. Ce₂(SO₄)₃-Catalyzed Friedel-Crafts Alkylation of Aromatic Compounds with Benzyl Alcohols, Allyl Alcohols and Benzyl Chlorides[J]. Chin. J. Org. Chem., 2005, 25(9): 1045-1048.

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硫酸亚铈催化的芳香化合物与苄基醇、烯丙醇类化合物以及苄基氯的傅-克烷基化反应研究

Ce₂(SO₄)₃-Catalyzed Friedel-Crafts Alkylation of Aromatic Compounds with Benzyl Alcohols, Allyl Alcohols and Benzyl Chlorides

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