Reaction of C60 with Abietic Acid Catalyzed by ZnCl2

Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (02): 252-254. Previous Articles Next Articles

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氯化锌催化下C₆₀与枞酸的反应

丁霞^a，林中祥*^,a，邓慧敏^b

(^a南京林业大学化工学院南京 210037)
(^b中山大学分析测试中心广州 510275)

收稿日期:2006-04-24 修回日期:2006-06-15 发布日期:2007-01-30
通讯作者: 林中祥

Reaction of C₆₀ with Abietic Acid Catalyzed by ZnCl₂

DING Xia^a, LIN Zhong-Xiang*^,a, DENG Hui-Min^b

(^a College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037)
(^b Instrumental Analysis & Research Center, Sun Yat-sen University, Guangzhou 510275)

Received:2006-04-24 Revised:2006-06-15 Published:2007-01-30
Contact: LIN Zhong-Xiang

Abstract

The reaction of C₆₀ with abietic acid was carried out in the presence of ZnCl₂ in o-dichloro- benzene under the atmosphere of N₂ at temperature of 175～180 ℃ for 8 h in order to obtain Diels-Alder adduct of C₆₀with pimaric acid to contain conjugated diene in the same ring derived from isomerization of abietic acid with conjugated diene in two different rings catalyzed by ZnCl₂. FT-IR, ¹³C NMR, ¹H NMR and MALDI-TOF-MS spectra were used to determine the obtained C₆₀adducts isolated through silica column chromatography. The results showed dehydrogenation and decarboxylation happened during the reaction and aromatic groups in obtained C₆₀adducts.

Key words: dehydrogenation, decarboxylation, abietic acid, C₆₀

Cite this article

DING Xia^a, LIN Zhong-Xiang*^,a, DENG Hui-Min^b. Reaction of C₆₀ with Abietic Acid Catalyzed by ZnCl₂ _{[J]. Chin. J. Org. Chem., 2007, 27(02): 252-254.}

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氯化锌催化下C₆₀与枞酸的反应

Reaction of C₆₀ with Abietic Acid Catalyzed by ZnCl₂

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氯化锌催化下C60与枞酸的反应