β-Cyclodextrin as Supramolecular Catalyst in Liquid-Phase Organic Synthesis

Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (12): 2072-2080. Previous Articles Next Articles

Review

β-环糊精超分子催化剂用于液相有机合成

纪红兵^*,a,b; 黄丽泉^a; 石东坡^a; 周贤太^b

(a华南理工大学传热强化与过程节能教育部重点实验室广州 510640)
(b中山大学化学与化工学院广州 510275)

收稿日期:2008-01-07 修回日期:2008-04-10 发布日期:2008-12-28
通讯作者: 纪红兵

β-Cyclodextrin as Supramolecular Catalyst in Liquid-Phase Organic Synthesis

JI, Hong-Bing^*,a,b ; HUANG, Li-Quan^a ; SHI, Dong-Po^a;ZHOU, Xian-Tai^b

(a Key Laboratory of Enhanced Heat Transfer and Energy Conservation of Ministry of Education, South China University of Technology, Guangzhou 510640)
(b School of Chemistry and Chemical Engineering, Sun Yan-Sen University, Guangzhou 510275)

Received:2008-01-07 Revised:2008-04-10 Published:2008-12-28
Contact: JI, Hong-Bing

Abstract

β-Cyclodextrin as a supramolecular catalyst is introduced in liquid-phase organic reactions including ring opening reactions, deprotective reactions, protective reactions, oxidations, reductions, addition reactions, substitution reactions and so on in detail. The catalytic performance and substrate-selectivities of β-cyclodextrin are analyzed, the interaction between β-cyclodextrin and substrates can effectively catalyze some liquid-phase organic reactions, and the selectivities could be enhanced accordingly. It is proposed that the functionized modification of β-cyclodextrin will lead to their wider application to the liquid-phase or-ganic reactions.

Key words: inclusion complex, supramolecular catalysis, water, β-cyclodextrin

Cite this article

JI, Hong-Bing^*,a,b ; HUANG, Li-Quan^a ; SHI, Dong-Po^a;ZHOU, Xian-Tai^b
. β-Cyclodextrin as Supramolecular Catalyst in Liquid-Phase Organic Synthesis[J]. Chin. J. Org. Chem., 2008, 28(12): 2072-2080.

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β-环糊精超分子催化剂用于液相有机合成

β-Cyclodextrin as Supramolecular Catalyst in Liquid-Phase Organic Synthesis

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