Synthesis, Structure and Redox Property of a New Tetrathiafulvalene Based Macrocyclic Compound

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (02): 234-238. Previous Articles Next Articles

Original Articles

基于四硫富瓦烯新型大环化合物的合成、结构与氧化还原性质

吕海燕

(中国科学院研究生院北京 100049)

收稿日期:2008-06-29 修回日期:2008-09-19 发布日期:2009-02-20
通讯作者: 吕海燕

Synthesis, Structure and Redox Property of a New Tetrathiafulvalene Based Macrocyclic Compound

LÜ, Haiyan

(The Graduate School of the Chinese Academy of Sciences, Beijing 100049)

Received:2008-06-29 Revised:2008-09-19 Published:2009-02-20
Contact: LÜ, Haiyan

Abstract

A new macrocyclic compound based on tetrathiafulvalene (TTF) and 2,5-bis(chloromethyl)- thiophene was synthesized and structurally characterized by elemental analysis, 1H NMR spectrum, MALDI-TOF MS and X-ray single-crystal diffraction analysis. The crystal of compound 1 belongs to monoclinic space group P2(1)/n with cell parameters a＝0.97220(19) nm, b＝1.2366(3) nm, c＝1.6051(3) nm, β＝95.41(3)°, V＝1.9211(7) nm3, Z＝2, Dc＝1.621 g/cm3, F(000)＝960, μ＝1.032 mm－1, R＝0.0333, and wR＝0.1000 [I＞2σ(I)]. Moreover, compound 1 displayed two couples of cathodic and anodic peaks in the cyclic voltammogram, and the redox processes are irreversible.

Key words: 2,5-bis(chloromethyl)thiophene, tetrathiafulvalene, macrocyclic compound, redox property, crystal structure

Cite this article

LÜ, Haiyan. Synthesis, Structure and Redox Property of a New Tetrathiafulvalene Based Macrocyclic Compound[J]. Chin. J. Org. Chem., 2009, 29(02): 234-238.

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基于四硫富瓦烯新型大环化合物的合成、结构与氧化还原性质

Synthesis, Structure and Redox Property of a New Tetrathiafulvalene Based Macrocyclic Compound

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