Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (06): 813-821.     Next Articles

Review

钯催化重氮化合物反应的研究进展

严国兵a ; 匡春香a ; 彭 程b; 王剑波*,b   

  1. (a同济大学化学系 上海200092)
    (b北京大学化学学院 生物有机与分子工程教育部重点实验室 北京分子科学国家实验室 北京100871)
  • 收稿日期:2008-08-05 修回日期:2008-10-26 发布日期:2009-06-20
  • 通讯作者: 王剑波

Recent Progress in Pd-Catalyzed Reactions of Diazo Compounds

Yan, Guobinga ; Kuang, Chunxianga ; Peng, Chengb; Wang, Jianbo*,b   

  1. (a Department of Chemistry, Tongji University, Shanghai 200092)
    (b Beijing National Laboratory of Molecular Sciences (BNLMS) & Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871)
  • Received:2008-08-05 Revised:2008-10-26 Published:2009-06-20
  • Contact: Wang, Jianbo

Recent development in palladium-catalyzed reactions of diazo compounds including cyclopropanation, polymerization, insertion reaction and cross-coupling reaction is reviewed. The mechanisms of these reactions are also discussed.

Key words: diazo compound, metal-carbene, reaction mechanism, palladium