Catalytic Synthesis of 14-Alkyl(aryl)-14H-dibenzo[a,j]xanthene Compounds by the H2SO4 loaded Coal Based Activated
Carbon as Solid Acid Catalyst under Solvent-Free Condition

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (10): 1637-1639. Previous Articles Next Articles

Notes

无溶剂条件下煤基活性炭负载硫酸作为固体酸催化合成 14-烷基(芳基)-14H-二苯并[a,j]氧杂蒽类化合物

楚惠元张会芳杨金会马峰李立强刘万毅

(宁夏大学化学化工学院宁夏能源化工自治区重点实验室银川 750021)

收稿日期:2008-12-21 修回日期:2009-03-10 发布日期:2009-05-05

Catalytic Synthesis of 14-Alkyl(aryl)-14H-dibenzo[a,j]xanthene Compounds by the H2SO4 loaded Coal Based Activated Carbon as Solid Acid Catalyst under Solvent-Free Condition

Chu, Huiyuan Zhang, Huifang Yang, Jinhui Ma, Feng Li, Liqiang Liu, Wanyi

(Key Laboratory of Energy Sources & Chemical Engineering, College of Chemistry and Chemical Engineering, University, Yinchuan 750021)

Received:2008-12-21 Revised:2009-03-10 Published:2009-05-05

Abstract

Eleven 14-alkyl(aryl)-14H-dibenzo[a,j] xanthenes were one-pot successfully synthesized from β-naphthol and alkyl(aryl) aldehydes using the H2SO4 loaded coal based activated carbon as the catalyst in a solvent-free medium. The reaction time was 0.1～1 h, and the yield ranged from 71% to 96%. The catalyst was inexpensive and environmentally friendly, and could be recycled at least five times without significant decrease in its catalytic activity. And catalyst for the acid value was 3.06 mmol/g.

Key words: xanthene, aldehyde, β-naphthol, H2SO4 loaded activated carbon, solvent-free reaction

Cite this article

CHU Hui-Yuan, ZHANG Hui-Fang, YANG Jin-Hui, MA Feng, LI Li-Jiang, LIU Mo-Yi. Catalytic Synthesis of 14-Alkyl(aryl)-14H-dibenzo[a,j]xanthene Compounds by the H2SO4 loaded Coal Based Activated Carbon as Solid Acid Catalyst under Solvent-Free Condition [J]. Chin. J. Org. Chem., 2009, 29(10): 1637-1639.

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无溶剂条件下煤基活性炭负载硫酸作为固体酸催化合成 14-烷基(芳基)-14H-二苯并[a,j]氧杂蒽类化合物

Catalytic Synthesis of 14-Alkyl(aryl)-14H-dibenzo[a,j]xanthene Compounds by the H2SO4 loaded Coal Based Activated Carbon as Solid Acid Catalyst under Solvent-Free Condition

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