Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (01): 142-148. Previous Articles     Next Articles

Reports

纤维素在超临界水中的反应

朱广用,马艳华,朱 宪*   

  1. (上海大学环境与化学工程学院 上海 200444)
  • 收稿日期:2008-12-24 修回日期:2009-05-24 发布日期:2010-01-20
  • 通讯作者: 朱广用 E-mail:xzhu@staff.shu.edu.cn;gyz@shu.edu.cn

Reactions of Cellulose in Supercritical Water

Zhu,Guangyong,Ma,Yanhua,Zhu,Xian   

  1. (School of Environmental & Chemical Engineering,Shanghai University,Shanghai 200444)
  • Received:2008-12-24 Revised:2009-05-24 Published:2010-01-20

Cellulose is a very valuable renewable resource。A variety of useful chemical compounds can be produced by the reactions of cellulose。The reactions of cellulose in supercritical water are reviewed。In the absence of a catalyst,the products for cellulose hydrolysis in supercritical water are glucose,fructose and oligomers。The experimental set-up,product distribution as well as mechanism of cellulose hydrolysis in supercritical water are discussed。Using a catalyst such as Ni,Pt,Ru,or KOH,the gasification reaction of cellulose in supercritical water occurred,and the main gas products produced were H2,CO2 and CH4。The hydrogen production processes from cellulose and glucose,which is the main product of cellulose hydrolysis reaction,are introduced。The prospect of cellulose reaction technology in supercritical water is discussed.

Key words: supercritical water, cellulose, conversion, reaction