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Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (10): 1497-1501. Previous Articles Next Articles
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邬继荣,陈巍峰,罗蒙贤,贺小林,李志芳
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低价金属钐催化光学活性聚硅烷的合成研究;新型碳硅(C/Si)陶瓷先驱体—可溶性聚硅烷的研制
WU Ji-Rong, CHEN Wei-Feng, LUO Meng-Xian, HE Xiao-Lin, LI Zhi-Fang
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Catalyzed by samarium(III) iodide (SmI3), Strecker-type reaction took place smoothly giving the corresponding α-aminonitriles in moderate to high yields at room temperature. Under this reaction conditions, aldehydes, ketones (aromatic and aliphatic) and amines (primary plus secondary) were the suitable substrates for Strecker-type reaction.
Key words: samarium(III) iodide, trimethylsilyl cyanide, α-aminonitrile
WU Ji-Rong, CHEN Wei-Feng, LUO Meng-Xian, HE Xiao-Lin, LI Zhi-Fang. Samarium(III) Iodide Catalyzed One-Pot Synthesis of α-Aminonitriles[J]. Chin. J. Org. Chem., 2010, 30(10): 1497-1501.
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