Chiral Recognition Based on Calixarene by NMR

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (07): 964-972. Previous Articles Next Articles

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杯芳烃手性识别在核磁中的检测

刘陆智，寇玉辉，汪凌云，曹德榕*

(华南理工大学化学与化工学院广州 510640)

收稿日期:2010-06-23 修回日期:2010-10-05 发布日期:2010-12-29
通讯作者: 刘陆智 E-mail:llzh068@163.com

Chiral Recognition Based on Calixarene by NMR

LIU Lu-Zhi, KOU Yu-Hui, WANG Ling-Yun, CAO De-Rong

(School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640)

Received:2010-06-23 Revised:2010-10-05 Published:2010-12-29
Contact: lu zhiLIU E-mail:llzh068@163.com

Calixarens are an important class of host compounds and have extensive applications in host-guest recognition. Especially, chiral calixarene is one of the most interesting research fields in calixarene chemistry because of its excellent chiral recognition, enantiomer separation and asymmetrical catalysis. In the study of chiral recognition, NMR spectrum is the most widely investigated measurement for determining ee values and assigning absolute configurations of chiral compounds due to its advantages of convenience, intuition and marked effect, etc. Herein, this paper deals with the latest research progress in the synthesis of chiral receptors based on calixarenes and their applications in the chiral recognition by NMR spectroscopy. In addition, the application prospects of chiral calixarenes are also dis-cussed.

Key words: chiral recognition, calixarene, enantiomeric detection, NMR

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LIU Lu-Zhi, KOU Yu-Hui, WANG Ling-Yun, CAO De-Rong. Chiral Recognition Based on Calixarene by NMR[J]. Chin. J. Org. Chem., 2011, 31(07): 964-972.

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杯芳烃手性识别在核磁中的检测

Chiral Recognition Based on Calixarene by NMR

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