Chin. J. Org. Chem. ›› 2008, Vol. 28 ›› Issue (07): 1254-1258. Previous Articles     Next Articles

Reports

新型含席夫碱大环化合物的合成

张奇龙 ; 朱兴城 ; 朱必学*   

  1. (贵州大学大环及超分子化学重点实验室 贵阳 55002)
  • 收稿日期:2007-08-27 修回日期:2007-11-29 发布日期:2008-07-28
  • 通讯作者: 朱必学

Synthesis of Novel Schiff Base Macrocyclic Compound

ZHANG, Qi-Long ; ZHU, Xing-Cheng; ZHU, Bi-Xue*   

  1. (Key Laboratory of Macrocyclic and Supramolecular Chemistry, Guizhou University, Guiyang 550025)
  • Received:2007-08-27 Revised:2007-11-29 Published:2008-07-28
  • Contact: ZHU, Bi-Xue

Two novel Schiff base macrocyclic compounds (6a and 6b) have been synthesized from ethylenediamine, 1,2-propane diamine, acetylacetone and 2,5-dimercapto-1,3,4-thiadiazole by condensation, bromination and cyclization, and their structures were characterized by elemental analysis, 1H NMR, IR and MS techniques. Simultaneously, the crystal structures of two intermediates were determined by X-ray diffraction analysis.

Key words: 2,5-dimercapto-1,3,4-thiadiazole, macrocyclic compound, crystal structure, acetylacetone