Chin. J. Org. Chem. ›› 2001, Vol. 21 ›› Issue (7): 533-534. Previous Articles     Next Articles

叔胺类环钯化合物在催化Heck反应的应用

张仰明;杨帆;郑瑞;汤杰   

  1. 华东师范大学化学系.上海(200062)
  • 发布日期:2001-07-25

Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts for the heck reaction

Zhang Yangming;Yang Fan;Zheng Rui;Tang Jie   

  1. E China Normal Univ, Dept Chem.Shanghai(200062)
  • Published:2001-07-25

Cyclopalladated complexes of tertiary arylamines 1~4 are reported for the first time with as highly efficinet catalysts for the Heck reactions turnover numbers being up to 9.6×10^6(mol product per mol Pd) and turnover frequencies up to 8.7×10^5(mol product per mol Pd per h). This is the highest catalytic activity of all Heck reactions reported to date.

Key words: TERTIARY AMINE, PALLADIUM COMPOUNDS, CATALYTIC REACTION

CLC Number: