Application in the Asymmetric Catalytic Reactions of Chiral Cyclopentadienyl-Transition-Metal Complexes

doi:10.6023/cjoc201903012

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (6): 1548-1556.DOI: 10.6023/cjoc201903012 Previous Articles Next Articles

Special Issue: 金属有机化学

Reviews

手性环戊二烯过渡金属配合物在不对称催化反应中的应用

单贺^a, 伶俐^a, 胡剑锋^a, 张浩^a,b

a 内蒙古大学化学化工学院呼和浩特 010021;
b 内蒙古自治区精细有机合成重点实验室呼和浩特 010021

收稿日期:2019-03-06 修回日期:2019-04-26 发布日期:2019-05-06
通讯作者: 张浩 E-mail:haozhang@imu.edu.cn
基金资助:
国家自然科学基金（No.21861028）和内蒙古自治区自然科学基金（No.2017MS0206）资助项目.

Application in the Asymmetric Catalytic Reactions of Chiral Cyclopentadienyl-Transition-Metal Complexes

Shan He^a, Ling Li^a, Hu Jianfeng^a, Zhang Hao^a,b

a College of Chemical & Chemical Engineering, Inner Mongolia University, Hohhot 010021;
b Inner Mongolia Key Laboratory of Fine Organic Synthesis, Hohhot 010021

Received:2019-03-06 Revised:2019-04-26 Published:2019-05-06
Contact: 10.6023/cjoc201903012 E-mail:haozhang@imu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21861028) and the Natural Science Foundation of Inner Mongolia (No. 2017MS0206).

The chiral Cp ligands as stereocontrolling element of asymmetric catalytic reactions have attracted increasing attention. Particularly, designing and synthesizing more versatile chiral Cp ligands became one of the most interested research focuses in asymmetric catalysis. The complexes of various chiral Cp ligands with different transition metals that advanced in recent years, and the applications of these complexes in catalytic asymmetric reactions are reviewed in this paper.

Key words: cyclopentadienyl ligands, asymmetric catalytic reactions, transition metal catalysis, synthesis

Cite this article

Shan He, Ling Li, Hu Jianfeng, Zhang Hao. Application in the Asymmetric Catalytic Reactions of Chiral Cyclopentadienyl-Transition-Metal Complexes[J]. Chin. J. Org. Chem., 2019, 39(6): 1548-1556.

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手性环戊二烯过渡金属配合物在不对称催化反应中的应用

Application in the Asymmetric Catalytic Reactions of Chiral Cyclopentadienyl-Transition-Metal Complexes

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