The research on the desilylation and esterification of  the trimethylsilyl cyclopropyl ethers

Chin. J. Org. Chem. ›› 1999, Vol. 19 ›› Issue (1): 34-39. Previous Articles Next Articles

Original Articles

环丙烷基三甲基硅醚类化合物的脱硅基及酯化反应的研究

孙海洲;李基森

中国科学院上海有机化学研究所.上海(200032)

发布日期:1999-02-25

The research on the desilylation and esterification of the trimethylsilyl cyclopropyl ethers

Sun Haizhou;Li Jisen

Shanghai Inst Organ Chem., CAS.Shanghai(200032)

Published:1999-02-25

Abstract

Trimethylsilyl cyclopropyl ethers can react with the silica gel to form the cyclopropanols when Lewis acid such as ZnX~2 existed. Then the esterification reaction between trimethylsilyl cyclopropyl ethers and acid chloride in the presence of ZnCl~2 were investigated, and better yields were obtained in less electron-donating solvent CH~2Cl~2 than in Et~2O. Moreover, we adopted an one-pot route combining the cyclopropanation and esterification of enoxysilane to prepare the cyclopropyl esters in moderate to good yields.

Key words: CYCLOPROPANE P, ACYL CHLORIDES, ZINC COMPOUNDS, ULTRASONIC WAVES, HALIDE, ESTERIFICATION

CLC Number:

O621

Cite this article

Sun Haizhou;Li Jisen. The research on the desilylation and esterification of the trimethylsilyl cyclopropyl ethers[J]. Chin. J. Org. Chem., 1999, 19(1): 34-39.

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环丙烷基三甲基硅醚类化合物的脱硅基及酯化反应的研究

The research on the desilylation and esterification of the trimethylsilyl cyclopropyl ethers

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