Chin. J. Org. Chem. ›› 1999, Vol. 19 ›› Issue (6): 616-620. Previous Articles     Next Articles

Original Articles

胺、醇和醚类化合物电离能的估算

曹晨忠   

  1. 湘潭师范学院化学系.湖南(411100)
  • 发布日期:1999-12-25

Estimation of the ionization potential for amines, alcohols and ethers

Cao Chenzhong   

  1. Xiangtan Normal College, Department of Chemistry.Xiangtan(411100)
  • Published:1999-12-25

The first ionization potentials Ip of aliphatic amines, alcohols, ethers, thio-alcohols and thio-ethers can be expressed as the function of atomic electronegativity X~z~O (z=N, O, or S atom), the atomic charge q~z (z=N, O or S atom) and the Polarizability Effect Index (PEI) of alkyl group: Ip(eV)=4.4851+3.0727X~Z~O+7.1702q~z-1. 3949∑PEI.

Key words: POLARIZATION EFFECT, IONIZATION ENERGY, ALIPHATIC AMINES, ELECTRONEGATIVITY, ALIPHATIC COMPOUNDS, ORGANIC COMPOUNDS, ALIPHATIC ALCOHOLS, ETHER

CLC Number: