Synthesis of 3,3,6,6-Tetramethyl-9-aryl-1,2,3,4,5,6,7,8-octahydro xanthene-1,8-dione Catalyzed by Expansible Graphite

Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (9): 1147-1149. Previous Articles Next Articles

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可膨胀石墨催化合成3,3,6,6-四甲基-9-芳基-1,2,3,4,5,6,7,8-八氢化氧杂蒽-1,8-二酮

张英群*，王春，马晶军，高月华，耿庆芬
唐然肖，高勇军

(河北农业大学理学院保定 071001)

收稿日期:2006-08-21 修回日期:2007-01-24 发布日期:2007-08-30
通讯作者: 张英群

Synthesis of 3,3,6,6-Tetramethyl-9-aryl-1,2,3,4,5,6,7,8-octahydro xanthene-1,8-dione Catalyzed by Expansible Graphite

ZHANG Ying-Qun*,WANG Chun,MA Jing-Jun,GAO Yue-Hua
GENG Qing-Fen,TANG Ran-Xiao,GAO Yong-Jun

(College of Science, Agricultural University of Hebei, Baoding 071001)

Received:2006-08-21 Revised:2007-01-24 Published:2007-08-30
Contact: 张英群

Abstract

A novel synthesis of 3,3,6,6-tetramethyl-9-aryl-1,2,3,4,5,6,7,8-octahydroxanthene-1,8-dione via condensation of aromatic aldehydes with 5,5-dimethyl-1,3-cyclohexanedione using expansible graphite as catalyst was described. The reaction time was 2.5 h, and the yield ranged from 87% to 93%. The catalyst was inexpensiv eand environmental friendly, and could be recovered by filtration.

Key words: 5,5-dimethyl-1,3-cyclohexanedione, 9-aryl-1,2,3,4,5,6, 7,8-octahydroxanthene-1,8-dione, aromatic aldehyde, expansible graphite

Cite this article

ZHANG Ying-Qun*,WANG Chun,MA Jing-Jun,GAO Yue-Hua
GENG Qing-Fen,TANG Ran-Xiao,GAO Yong-Jun. Synthesis of 3,3,6,6-Tetramethyl-9-aryl-1,2,3,4,5,6,7,8-octahydro xanthene-1,8-dione Catalyzed by Expansible Graphite[J]. Chin. J. Org. Chem., 2007, 27(9): 1147-1149.

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可膨胀石墨催化合成3,3,6,6-四甲基-9-芳基-1,2,3,4,5,6,7,8-八氢化氧杂蒽-1,8-二酮

Synthesis of 3,3,6,6-Tetramethyl-9-aryl-1,2,3,4,5,6,7,8-octahydro xanthene-1,8-dione Catalyzed by Expansible Graphite

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