Chin. J. Org. Chem. ›› 1990, Vol. 10 ›› Issue (4): 342-345. Previous Articles     Next Articles

Original Articles

利用^1H CIDNP效应对芳基重氮盐还原反应的研究

徐广智;李二成;蒋宏键;严宝珍   

  1. 中国科学院化学研究所;北京化工学院应用化学系
  • 发布日期:1990-08-25

CIDNP Study on reduction reaction of diazonium salts

XU GUANGZHI;LI ERCHENG;JIANG HONGJIAN;YAN BAOZHEN   

  • Published:1990-08-25

The substituent effect on the reduction of arenediazonium tetrafluoroborates was discussed with 1H CIDNP. It was observed that the polarized time were influenced by characteristic of substituent and nuclear relaxation effect.

Key words: NMR SPECTROMETRY, DIAZO COMPOUNDS, STERIC EFFECT, AROMATIC COMPOUNDS, CIDNP, REDUCTION REACTION, FREE RADICAL REACTION, SODIUM BOROHYDRIDE, SUBSTITUENT EFFECT, REACTION RATE

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