Chin. J. Org. Chem. ›› 1990, Vol. 10 ›› Issue (5): 435-439. Previous Articles     Next Articles

Original Articles

光学活性1,2,3,3a,4,5-六氢铁屎米-6-酮环系合成的新途径

刘铸晋;徐风   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1990-10-25

A novel route to the synthesis of optically actie 1,2,3,3a,4,5-hexahydro-canthin-6-one derivatives

LIU ZHUJIN;XU FENG   

  • Published:1990-10-25

Title compounds I [R = (Z)-CH2CH:CHCH2OAc, (E)-CH2CH:CHMe, CH2CH:CH2] were prepared in 70-98% yield by treating hydrocarbolinepropionates II with NaH in hexamethylphosphoramide.

Key words: INFRARED SPECTROPHOTOMETRY, INDOLE P, MASS SPECTROGRAPHY, STEREOCHEMISTRY, CANTHINE ALKALOID, PROTON MAGNETIC RESONANCE SPECTROMETRY, C13 NMR SPECTROMETRY, STEREOSELECTIVITY, KETONE

CLC Number: