Chin. J. Org. Chem. ›› 2000, Vol. 20 ›› Issue (4): 560-563. Previous Articles     Next Articles

高碘酸盐氧化1,6-二-O-三苯甲基-D-甘露醇的区选性

赵凯元;王 清   

  1. 苏州铁道师范学院化学系
  • 发布日期:2000-08-25

Rigioselectivity of periodate oxidation of 1,6-bis-O- (triphenylmethyl)-D-mannitol

Zhao Kaiyuan;Wang   

  • Published:2000-08-25

A model compound 1,6-bis-O-(triphenylmethyl)-D-mannitol(TPMM) is synthesized, and the regioselectivity of periodate oxidation reaction of TPMM in mixed solvents is studied. The oxidation products are separated and analyzed. The main oxide product, α-O- (triphenylmethyl)-acetaldehyde(TPMA), and α-hydroxyl acetaldehyde, prepared from TPMA, are important organic synthetic intermediate.

Key words: PERIODATE, OXIDATION, MANNITOL P, SELECTIVITY

CLC Number: