Suzuki Coupling Reaction Catalyzed by Palladium Supported on Positively Charged Colloids of Magnetic Iron Oxide

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (10): 1587-1592. Previous Articles Next Articles

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正电性磁性氧化铁胶粒负载钯催化的Suzuki偶联反应

刘诗咏^*,a 吴家守^a蒋华江^a金正能^a 姜玄珍^b

(a浙江省台州学院城东校区医化学院临海 317000) (b浙江大学玉泉校区理学院化学系杭州 310027)

收稿日期:2009-02-07 修回日期:2009-03-30 发布日期:2009-05-15

Suzuki Coupling Reaction Catalyzed by Palladium Supported on Positively Charged Colloids of Magnetic Iron Oxide

Liu, Shiyong^*,a Wu, Jiashou^a Jiang, Huajiang^aJin, Zhengneng^a Jiang, Xuanzhen^b

(^a College of Chemistry & Pharmacy, Taizhou University, Linhai 317000) (^b Department of Chemistry, Zhejiang University, Hangzhou 310027)

Received:2009-02-07 Revised:2009-03-30 Published:2009-05-15

Abstract

A facile way to combine Pd0 with superparamagnetic Fe3O4 nanoparticles (NP) was provided, in which was immobilized directly on the cationic Fe3O4 colloids through electrostatic interaction ( /Fe3O4). Further reduction of the /Fe3O4 NP by vitamin C resulted in Pd0/Fe3O4 NP. These magnetic NP-supported Pd0 clusters showed high efficiency toward Suzuki reactions. After reactions, the Pd0/Fe3O4 NP could be facilely recycled by permanent magnet. This catalyst could be reused for 5 times without significant loss in catalytic activity. Suzuki coupling reaction of a variety of aryl halides was also catalyzed efficiently by this magnetic NP supported Pd0.

Key words: Pd, nanoparticle, cationic colloid, magnetic iron oxide, Suzuki reaction

Cite this article

LIU Shi-Yong, TUN Jia-Shou, JIANG Hua-Jiang, Jin-Zheng-Nai, Jiang-Xuan-Zhen. Suzuki Coupling Reaction Catalyzed by Palladium Supported on Positively Charged Colloids of Magnetic Iron Oxide[J]. Chin. J. Org. Chem., 2009, 29(10): 1587-1592.

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正电性磁性氧化铁胶粒负载钯催化的Suzuki偶联反应

Suzuki Coupling Reaction Catalyzed by Palladium Supported on Positively Charged Colloids of Magnetic Iron Oxide

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