Synthesis and Photochromic Property of Three Novel Calix[4]arene-Schiff Bases

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (11): 1799-1803. Previous Articles Next Articles

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新型杯[4]席夫碱的合成及光致变色性质研究

刘志莲^*,a,b 张书香^a 夏光明^a 梁志^c 高云华^b,c

(a济南大学化学化工学院济南 250022) (b中国科学院光化学转换与功能材料重点实验室北京 100190) (c中国科学院理化技术研究所北京 100190)

收稿日期:2009-01-15 修回日期:2009-03-30 发布日期:2009-06-19
通讯作者: 刘志莲 E-mail:zhilianliu@163.com
基金资助:
济南大学博士基金（No.B0637）;国家级.国家自然科学基金

Synthesis and Photochromic Property of Three Novel Calix[4]arene-Schiff Bases

Liu, Zhilian^*,a,b Zhang, Shuxiang^a Xia, Guangming^a Liang, Zhi^c Gao, Yunhua ^b,c

(^a College of Chemistry And Chemical Engineering, University of Jinan, Jinan 250022) (^b Key Labortory of Photochemical Conversion and Optoelectronic Materials, Chinese Academy of Sciences, Beijing 100190) (^c Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190)

Received:2009-01-15 Revised:2009-03-30 Published:2009-06-19

Abstract

Three novel Schiff-bases carrying calix[4]arene and the model compounds without calix[4]arene moieties have been synthesized. The structures of the new compounds were confirmed by IR, 1H NMR, 13C NMR, MALDI-TOF MS and elemental analysis. The calix[4]arene-Schiff bases have photochromic behaviors. Calix[4]arene moieties, substituent OCH3 and solvent CH2Cl2 could effectively improve the photochromic properties of these Schiff-bases.

Key words: Schiff-base, calix[4]arene, photochormism, hydrogen bond

Cite this article

LIU Zhi-Lian, ZHANG Shu-Xiang, JIA Guang-Meng, LIANG Zhi, GAO Yun-Hua. Synthesis and Photochromic Property of Three Novel Calix[4]arene-Schiff Bases[J]. Chin. J. Org. Chem., 2009, 29(11): 1799-1803.

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新型杯[4]席夫碱的合成及光致变色性质研究

Synthesis and Photochromic Property of Three Novel Calix[4]arene-Schiff Bases

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