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Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (10): 1497-1501. Previous Articles     Next Articles

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三碘化钐催化的一锅法合成α-胺基腈化合物

邬继荣，陈巍峰，罗蒙贤，贺小林，李志芳   

  1. (杭州师范大学有机硅化学及材料技术教育部重点实验室 杭州 310012)
  • 收稿日期:2010-01-21 修回日期:2010-04-08 发布日期:2010-05-14
  • 通讯作者: 李志芳 E-mail:zhifanglee@hznu.edu.cn
  • 基金资助:

    低价金属钐催化光学活性聚硅烷的合成研究;新型碳硅(C/Si)陶瓷先驱体—可溶性聚硅烷的研制

Samarium(III) Iodide Catalyzed One-Pot Synthesis of α-Aminonitriles

WU Ji-Rong, CHEN Wei-Feng, LUO Meng-Xian, HE Xiao-Lin, LI Zhi-Fang   

  1. (Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 310012)
  • Received:2010-01-21 Revised:2010-04-08 Published:2010-05-14

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Catalyzed by samarium(III) iodide (SmI3), Strecker-type reaction took place smoothly giving the corresponding α-aminonitriles in moderate to high yields at room temperature. Under this reaction conditions, aldehydes, ketones (aromatic and aliphatic) and amines (primary plus secondary) were the suitable substrates for Strecker-type reaction.

Key words: samarium(III) iodide, trimethylsilyl cyanide, α-aminonitrile