Suzuki Reaction Catalyzed by Nanopalladium Stabilized by Gemini Quaternary Ammonium Salt

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (06): 850-854. Previous Articles Next Articles

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双子季铵盐稳定的纳米钯催化Suzuki反应的研究

周波，李毅群*

(暨南大学化学系广州 510632)

收稿日期:2010-09-11 修回日期:2010-12-30 发布日期:2011-02-14
通讯作者: 李毅群 E-mail:tlyq@jnu.edu.cn

Suzuki Reaction Catalyzed by Nanopalladium Stabilized by Gemini Quaternary Ammonium Salt

ZHOU Bo, LI Yi-Qun

(Department of Chemistry, Jinan University, Guangzhou 510632)

Received:2010-09-11 Revised:2010-12-30 Published:2011-02-14
Contact: Li Yi-Qun E-mail:tlyq@jnu.edu.cn

Palladium nanoparticles with the size ranged from 5 nm to 25 nm confirmed by transmission electron microscopy (TEM), generated in situ from the reaction of palladium(II) chloride and stabilized by Gemini quaternary ammonium salt, have been demonstrated to be an ef?cient catalyst for Suzuki car-bon-carbon cross coupling reaction. A variety of aryl bronic acids and aryl halides have been proceed smoothly to afford the corresponding biaryls in high yields by using palladium nanoparticles in the presence of potassium carbonate without any ligands. This protocol has the merits of that the catalyst is stable in air and the procedure of experiment is simple.

Key words: Suzuki reaction, nanopalladium, Gemini quaternary ammonium salt

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ZHOU Bo, LI Yi-Qun. Suzuki Reaction Catalyzed by Nanopalladium Stabilized by Gemini Quaternary Ammonium Salt[J]. Chin. J. Org. Chem., 2011, 31(06): 850-854.

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双子季铵盐稳定的纳米钯催化Suzuki反应的研究

Suzuki Reaction Catalyzed by Nanopalladium Stabilized by Gemini Quaternary Ammonium Salt

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