Nanoparticles Pd-Catalyzed Highly Efficient Suzuki Cross-Coupling Reaction

doi:10.6023/cjoc201502022

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (8): 1650-1656.DOI: 10.6023/cjoc201502022 Previous Articles Next Articles

ARTICLE

纳米钯催化的高效Suzuki偶联反应

赵晓霞^a, 常宏宏^b, 李兴^b, 魏文珑^b

a 太原科技大学化学与生物工程学院太原 030021;
b 太原理工大学化学化工学院太原 030024

收稿日期:2015-02-14 修回日期:2015-06-04 发布日期:2015-06-12
通讯作者: 赵晓霞 E-mail:kdhyzxx@163.com
基金资助:
山西省自然科学基金(No. 2012021007-2)资助项目.

Nanoparticles Pd-Catalyzed Highly Efficient Suzuki Cross-Coupling Reaction

Zhao Xiaoxia^a, Chang Honghong^b, Li Xing^b, Wei Wenlong^b

a College of Chemistry and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021;
b College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024

Received:2015-02-14 Revised:2015-06-04 Published:2015-06-12
Supported by:
Project supported by the Natural Science Foundation of Shanxi Province (No. 2012021007-2).

1. Nanoparticles Pd-Catalyzed Highly Efficient Suzuki Cross-Coupling Reaction.PDF(554KB)

Abstract

An efficient protocol for the Suzuki reactions catalyzed by Pd(PPh₃)₄-derived nanoparticles palladium catalyst has been developed. This method is able to prepare a variety of biaryls under air atmosphere at 25~90 ℃ in DMF/H₂O mixture solvent. In the presence of this catalyst, the cross-coupling reactions of aryl halides with arylboronic acids proceed smoothly and afforded the desired coupling products with high yields. The catalyst could be recycled 6 times without loss of activity and decrease of yield.

Key words: nanoparticles palladium, Suzuki reaction, Pd/Al₂O₃, biphenyls, H₂O

Cite this article

Zhao Xiaoxia, Chang Honghong, Li Xing, Wei Wenlong. Nanoparticles Pd-Catalyzed Highly Efficient Suzuki Cross-Coupling Reaction[J]. Chin. J. Org. Chem., 2015, 35(8): 1650-1656.

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纳米钯催化的高效Suzuki偶联反应

Nanoparticles Pd-Catalyzed Highly Efficient Suzuki Cross-Coupling Reaction

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