One-Pot Synthesis of Pinonic Acid Esters Catalyzed by N,N-Dimethyl-4-aminopyridine

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (07): 1091-1094. Previous Articles Next Articles

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一锅法N,N-二甲基-4-氨基吡啶催化合成蒎酮酸酯

于静^1,2，沈敏敏*^,1，哈成勇¹，邓莲丽^1,2，刘海峰^1,2

(¹中国科学院广州化学研究所中国科学院纤维素化学重点实验室广州 510650)
(²中国科学院研究生院北京 100039)

收稿日期:2010-11-03 修回日期:2011-01-18 发布日期:2011-02-15
通讯作者: 沈敏敏 E-mail:shenmm@gic.ac.cn

One-Pot Synthesis of Pinonic Acid Esters Catalyzed by N,N-Dimethyl-4-aminopyridine

Yu Jing^1,2 Shen Minmin*^,1 Ha Chen-gyong¹ Deng Lianli^1,2 Liu Haifeng^1,2

(¹Laboratory of Cellulose and Lignocellulosics Chemistry, Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650)
(²Graduate School of the Chinese Academy of Sciences, Beijing 100039)

Received:2010-11-03 Revised:2011-01-18 Published:2011-02-15

Six pinonic acid esters were synthesized from one-pot ozonolysis reaction using α-pinene and alcohol as materials, dichloromethane as solvent and N,N-dimethyl-4-aminopyridine (DMAP) as catalyst with the yield of 60%. The reaction temperature was 40 ℃ and reaction time was 4 h. This method is a convenient and efficient way to synthesize pinonic acid esters, such as simple operation, mild conditions and high yields. The structures of the six pinonic acid esters were identified by IR, NMR and MS techniques.

Key words: DMAP, one-pot synthesis, ozonolysis, pinonic acid ester

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YU Jing, SHEN Min-Min, HA Cheng-Yong, DENG Lian-Li, LIU Hai-Feng. One-Pot Synthesis of Pinonic Acid Esters Catalyzed by N,N-Dimethyl-4-aminopyridine[J]. Chin. J. Org. Chem., 2011, 31(07): 1091-1094.

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一锅法N,N-二甲基-4-氨基吡啶催化合成蒎酮酸酯

One-Pot Synthesis of Pinonic Acid Esters Catalyzed by N,N-Dimethyl-4-aminopyridine

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