Pd/C-Catalyzed Highly Efficient and Green Suzuki Cross-Coupling Reaction

doi:10.6023/cjoc201206029

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (9): 1666-1672.DOI: 10.6023/cjoc201206029 Previous Articles Next Articles

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钯/碳高效绿色催化Suzuki交叉偶联反应

初文毅^a,b, 王熳^a,b, 李新民^a,b, 侯艳君^a,b, 孙志忠^a,b

a 黑龙江大学化学化工与材料学院哈尔滨 150080;
b 黑龙江省普通高等学校高效转化的化工过程与技术重点实验室哈尔滨 150080

收稿日期:2012-06-30 修回日期:2012-07-18 发布日期:2012-07-14
通讯作者: 孙志忠 E-mail:sunzz@hlju.edu.cn
基金资助:
黑龙江省教育厅科技(No.12511383)和哈尔滨市科技局科技创新人才研究专项基金(No.RC2012XK001005)资助项目

Pd/C-Catalyzed Highly Efficient and Green Suzuki Cross-Coupling Reaction

Wang Man^a,b, Li Xinmin^a,b, Hou Yanjun^a,b, Sun Zhizhong^a,b

a School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080;
b Key Laboratory of Chemical Engineering Process & Technology for High-efficiency Conversion, College of Heilongjiang Province, Harbin 150080

Received:2012-06-30 Revised:2012-07-18 Published:2012-07-14
Supported by:
Project supported by the Research Project of Education Department of Heilongjiang Province of China (No.12511383) and the Research Special Funds for Innovation Talent of Harbin of China (No.RC2012XK001005)

An efficient protocol for the Suzuki reaction catalyzed by Pd/C has been developed in a green sovent. This method is able to prepare a variety of biaryls in high yields. In the presence of 1-butyl-3-methylimidazolium bis[(trifluoro-methyl)sulfonyl]imide, the cross-coupling reaction of aryl bromides with arylboronic acids proceed smoothly in PEG400 aqueous at 45℃. The catalyst could be recycled four times without loss of activity.

Key words: Pd/C, Suzuki reaction, biphenyls, ionic liquid

Cite this article

Wang Man, Li Xinmin, Hou Yanjun, Sun Zhizhong. Pd/C-Catalyzed Highly Efficient and Green Suzuki Cross-Coupling Reaction[J]. Chin. J. Org. Chem., 2012, 32(9): 1666-1672.

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钯/碳高效绿色催化Suzuki交叉偶联反应

Pd/C-Catalyzed Highly Efficient and Green Suzuki Cross-Coupling Reaction

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