Nanoparticles Pd-Catalyzed Suzuki and Heck Cross-Coupling Reactions of Arenediazonium Tetrafluoroborate Salts

doi:10.6023/cjoc201407023

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (2): 478-483.DOI: 10.6023/cjoc201407023 Previous Articles Next Articles

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纳米钯催化芳基重氮盐的Suzuki和Heck偶联反应

赵晓霞^a, 常宏宏^b, 李兴^b, 魏文珑^b

a 太原科技大学化学与生物工程学院太原 030021;
b 太原理工大学化学化工学院太原 030024

收稿日期:2014-07-12 修回日期:2014-09-11 发布日期:2014-10-23
通讯作者: 赵晓霞 E-mail:kdhyzxx@163.com
基金资助:
山西省自然科学基金(Nos. 2012021007-2, 2011011010-2)及山西省高等教育机构科技创新基金(No. 20120006)资助项目.

Nanoparticles Pd-Catalyzed Suzuki and Heck Cross-Coupling Reactions of Arenediazonium Tetrafluoroborate Salts

Zhao Xiaoxia^a, Chang Honghong^b, Li Xing^b, Wei Wenlong^b

a College of Chemistry and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021;
b College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024

Received:2014-07-12 Revised:2014-09-11 Published:2014-10-23
Supported by:
Project supported by the Natural Science Foundation of Shanxi Province (Nos. 2012021007-2, 2011011010-2) and the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (No. 20120006)..

1. Nanoparticles Pd-Catalyzed Suzuki and Heck Cross-Coupling Reactions of Arenediazonium Tetrafluoroborate Salts.PDF(805KB)

Abstract

An efficient protocol for the Suzuki and Heck reactions of arenediazonium tetrafluoroborate salts catalyzed by Pd(PPh₃)₄-derived nanoparticles palladium catalyst has been developed. This method is able to prepare a variety of biaryls and aryl olefin under air atmosphere at 25 ℃ in ethanol. In the presence of this catalyst, the cross-coupling reactions of arenediazonium tetrafluoroborate salts with arylboronic acids and olefin proceed smoothly and afford the desired coupling products with good yields, respectively. The catalyst could be recycled 4 times without loss of activity and decrease of yield.

Key words: nanoparticle palladium, Suzuki, Heck, Pd/Al₂O₃, biphenyls, aryl olefin

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Zhao Xiaoxia, Chang Honghong, Li Xing, Wei Wenlong. Nanoparticles Pd-Catalyzed Suzuki and Heck Cross-Coupling Reactions of Arenediazonium Tetrafluoroborate Salts[J]. Chin. J. Org. Chem., 2015, 35(2): 478-483.

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纳米钯催化芳基重氮盐的Suzuki和Heck偶联反应

Nanoparticles Pd-Catalyzed Suzuki and Heck Cross-Coupling Reactions of Arenediazonium Tetrafluoroborate Salts

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