Application of (C4H12N2)2[BiCl6]Cl·H2O/SiO2 in the Synthesis ofHydratropic Aldehyde and Its Analogs

doi:10.6023/cjoc201505036

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (11): 2393-2398.DOI: 10.6023/cjoc201505036 Previous Articles Next Articles

Notes

(C₄H₁₂N₂)₂[BiCl₆]Cl·H₂O/SiO₂在龙葵醛及其类似物合成中的应用

聂士鹏^a, 沈薇^b, 高玉华^a, 唐演^a, 张翔^a, 谷晓玉^a, 陆鸿飞^a

a 江苏科技大学环境与化学工程学院镇江 212003;
b 南京农业大学理学院南京 210095

收稿日期:2015-03-25 修回日期:2015-06-27 发布日期:2015-07-10
通讯作者: 陆鸿飞 E-mail:zjluhf1979@hotmail.com
基金资助:
国家自然科学基金(No. 21402067)资助项目.

Application of (C₄H₁₂N₂)₂[BiCl₆]Cl·H₂O/SiO₂ in the Synthesis ofHydratropic Aldehyde and Its Analogs

Nie Shipeng^a, Shen Wei^b, Gao Yuhua^a, Tang Yan^a, Zhang Xiang^a, Gu Xiaoyu^a, Lu Hongfei^a

a School of Envionmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003;
b School of College of Sciences, Nanjing Agriculture University, Nanjing 210095

Received:2015-03-25 Revised:2015-06-27 Published:2015-07-10
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21402067).

1. Application of (C₄H₁₂N₂)₂[BiCl₆]Cl·H₂O/SiO₂ in the Synthesis ofHydratropic Aldehyde and Its Analogs.PDF(1101KB)

Abstract

A highly efficient and facile procedure for the rearrangement various epoxides to carbonyl aldehydes by the catalytic system (C₄H₁₂N₂)₂[BiCl₆]Cl·H₂O/SiO₂ at room temperature is developed. The methodology is applicable to a wide range of substrates. The catalyst is air-stable and environmentally friendly and can be recycled multiple times without noticeably losing its catalytic activity.

Key words: hydratropic aldehyde, Lewis acid catalyst, epoxides, rearrangement

Cite this article

Nie Shipeng, Shen Wei, Gao Yuhua, Tang Yan, Zhang Xiang, Gu Xiaoyu, Lu Hongfei. Application of (C₄H₁₂N₂)₂[BiCl₆]Cl·H₂O/SiO₂ in the Synthesis ofHydratropic Aldehyde and Its Analogs[J]. Chin. J. Org. Chem., 2015, 35(11): 2393-2398.

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(C₄H₁₂N₂)₂[BiCl₆]Cl·H₂O/SiO₂在龙葵醛及其类似物合成中的应用

Application of (C₄H₁₂N₂)₂[BiCl₆]Cl·H₂O/SiO₂ in the Synthesis ofHydratropic Aldehyde and Its Analogs

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(C4H12N2)2[BiCl6]Cl·H2O/SiO2在龙葵醛及其类似物合成中的应用