A Fluorescence Enhancement Probe for Trivalent Ions: Preparation and Property

doi:10.6023/cjoc201612004

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (3): 726-730.DOI: 10.6023/cjoc201612004 Previous Articles Next Articles

Notes

一种荧光增强型三价金属离子荧光探针的合成及性质

侯淑华, 王思琦, 曲忠国, 钟克利, 边延江, 汤立军

渤海大学化学化工学院锦州 121013

收稿日期:2016-12-02 修回日期:2017-01-24 发布日期:2017-02-15
通讯作者: 汤立军,E-mail:bhutang@126.com E-mail:bhutang@126.com
基金资助:
辽宁省高等学校优秀人才支持计划（No.LR2015001）资助项目.

A Fluorescence Enhancement Probe for Trivalent Ions: Preparation and Property

Hou Shuhua, Wang Siqi, Qu Zhongguo, Zhong Keli, Bian Yanjiang, Tang Lijun

Department of Chemistry, Bohai University, Jinzhou 121013

Received:2016-12-02 Revised:2017-01-24 Published:2017-02-15
Contact: 10.6023/cjoc201612004 E-mail:bhutang@126.com
Supported by:
Project supported by the Program for Liaoning Excellent Talents in University (No. LR2015001).

1. A Fluorescence Enhancement Probe for Trivalent Ions: Preparation and Property.PDF(756KB)

Abstract

A novel rhodamine-based probe L was synthesized and characterized. The results showed that probe L acted as a fluorescent enhancement probe for Cr³⁺, Fe³⁺ and Al³⁺ recognition in CH₃OH/H₂O (V:V=8:2, c(Tris)=10 mmol/L, pH=7.2). L is highly selective to trivalent ions Cr³⁺, Fe³⁺ and Al³⁺ over other monovalent or divalent ions. Detection limits of probe L for Cr³⁺, Fe³⁺ and Al³⁺ are 2.1×10^-4, 2.3×10^-4 and 4.4×10^-4 mol/L, respectively, which make it have potentially application value in Cr³⁺, Fe³⁺ and Al³⁺ detection in various water samples.

Key words: rhodamine, trivalent ions, fluorescence enhancement

Cite this article

Hou Shuhua, Wang Siqi, Qu Zhongguo, Zhong Keli, Bian Yanjiang, Tang Lijun. A Fluorescence Enhancement Probe for Trivalent Ions: Preparation and Property[J]. Chin. J. Org. Chem., 2017, 37(3): 726-730.

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一种荧光增强型三价金属离子荧光探针的合成及性质

A Fluorescence Enhancement Probe for Trivalent Ions: Preparation and Property

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