Recent Achievements in the Synthesis of Sulfoximine Derivatives

doi:10.6023/cjoc201710002

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (4): 719-737.DOI: 10.6023/cjoc201710002 Previous Articles Next Articles

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亚氨基砜衍生物的合成研究进展(封面文章)

周豪, 陈知远

江西师范大学化学化工学院功能有机小分子教育部重点实验室南昌 330022

收稿日期:2017-10-06 修回日期:2017-11-29 发布日期:2017-12-15
通讯作者: 陈知远 E-mail:zchen@jxnu.edu.cn
基金资助:
国家自然科学基金（Nos.21462022，21672085）资助项目.

Recent Achievements in the Synthesis of Sulfoximine Derivatives

Zhou Hao, Chen Zhiyuan

Key Laboratory of Functional Small Organic Molecules, Ministry of Education, College of Chemistry & Chemical Engineering, Jiangxi Normal University, Nanchang 330022

Received:2017-10-06 Revised:2017-11-29 Published:2017-12-15
Contact: 10.6023/cjoc201710002 E-mail:zchen@jxnu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21462022, 21672085).

The sulfoximine derivatives are widely known for their potent biological and medicinal activities. Recently, due to the transition-metal catalysis, great advancements have been achieved in the synthesis of sulfoximine derivatives. Utilizing free NH-sulfoximines as the starting materials, various the direct N-H functionalizations can be accomplished, such as alkynylation, alkenylation, alkylation, arylation, etc. In addition, the ortho arene C(sp²)-H activation can also be obtained through C-H activation reaction with the assistance of S=NH as intramolecular directing groups, thus giving varies (hetero)aromatic molecules. N-H and C-H functionalization reactions of sulfoximines were summarized, and the mechanisms of some novel model reactions are also briefly discussed.

Key words: NH-sulfoximine, transition-metal-catalysis, C-H functionalization

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Zhou Hao, Chen Zhiyuan. Recent Achievements in the Synthesis of Sulfoximine Derivatives[J]. Chin. J. Org. Chem., 2018, 38(4): 719-737.

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亚氨基砜衍生物的合成研究进展(封面文章)

Recent Achievements in the Synthesis of Sulfoximine Derivatives

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