Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (11): 3620-3632.DOI: 10.6023/cjoc202006068 Previous Articles     Next Articles

Special Issue: 有机光催化虚拟合辑 创刊四十周年专辑


袁晓亚a, 杨国平b, 於兵a   

  1. a 郑州大学化学学院 绿色催化中心 郑州 450001;
    b 东华理工大学江西省质谱科学与仪器重点实验室 南昌 330013
  • 收稿日期:2020-06-29 修回日期:2020-09-03 发布日期:2020-09-09
  • 通讯作者: 於兵
  • 基金资助:

Photoinduced Decatungstate-Catalyzed C-H Functionalization

Yuan Xiaoyaa, Yang Guopingb, Yu Binga   

  1. a Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001;
    b Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang 330013
  • Received:2020-06-29 Revised:2020-09-03 Published:2020-09-09
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21971224).

In recent years, decatungstate [W10O32]4- as a catalyst has attracted much attention in the field of photocatalytic organic synthesis. With the catalysis of decatungstate, the C—H bond of substrate can be converted into the corresponding radical via a hydrogen atom transfer (HAT) progress under light irradiation. In this review, we summarized the recent advances of the application of decatungstate as a photocatalyst for the C—H functionalization to construct C—C, C—N, C—F bonds.

Key words: decatungstate, hydrogen atom transfer (HAT), photocatalysis, radical, C-H functionalization