Recent Advances in the Synthesis of Heterocyclic Compounds via Pd-Catalyzed C(sp3)-H Bond Activation

doi:10.6023/cjoc201805028

Abstract

Heterocyclic compounds are not only important intermediates in organic synthesis and medicine synthesis, but also the basic building framework of biologically active natural products. In recent years, Pd-catalyzed C(sp³)-H bonds activation has been demonstrated as one of the hot topics in the field of heterocyclic compound synthesis because of its high atomic economic characteristics. Herein, the recent research progress in the construction of heterocyclic compounds via Pd-catalyzed C(sp³)-H bond activation is summarized according to the classification of the ring number of heterocyclic compounds (mainly including N, O heterocycles). The reaction selectivity, substrate compatibility, reaction mechanism, advantages and disadvantages as well as an outlook in this field are also discussed.

Key words: Pd-catalyzed, C (sp³)-H bond activation, heterocyclic compounds

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Zhao Kang, Yang Lei, Liu Jianhua, Xia Chungu. Recent Advances in the Synthesis of Heterocyclic Compounds via Pd-Catalyzed C(sp³)-H Bond Activation[J]. Chin. J. Org. Chem., 2018, 38(11): 2833-2857.

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Pd催化C(sp³)—H键活化构建杂环化合物的研究进展

Recent Advances in the Synthesis of Heterocyclic Compounds via Pd-Catalyzed C(sp³)-H Bond Activation

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[11]	Geng Dianguo. Recent Advances on Transition-Metal-Catalyzed Allenamides Cyclization [J]. Chin. J. Org. Chem., 2019, 39(2): 301-317.
[12]	Tu Shuangyan, Xu Wushuang, Qi Fen, He Weijiang, Fei Baoli. Interaction of Optically Pure Dehydroabietylamine Heterocyclic Derivatives with DNA and Preliminary Cytotoxic Activity [J]. Chinese Journal of Organic Chemistry, 2019, 39(11): 3269-3276.
[13]	Lei Lu, Li Chengjing, Mo Dongliang. Recent Advances in Copper-Catalyzed N-O Cleavage Strategy [J]. Chinese Journal of Organic Chemistry, 2019, 39(11): 2989-3012.
[14]	Shi Haixiong, Cheng Xiaobin, Lin Qi, Yao Hong, Zhang Youming, Wei Taibao. Study on the Effect of Host-Guest Based on the Dimethoxy-pillar[5]arene and Benzazole Heterocyclic Compounds [J]. Chin. J. Org. Chem., 2018, 38(7): 1718-1724.
[15]	Qiu Huihua, Cheng Borui, Huang Yingsi, Chen Cui, Zhou Peng. Research on the Tandem Reaction via Chloropalladation/Heck Cross Coupling of o-(Alkynyl)styrenes with Pd/O₂ [J]. Chin. J. Org. Chem., 2018, 38(7): 1817-1822.

Pd催化C(sp3)—H键活化构建杂环化合物的研究进展