Synthesis of Osmium Complexes with Bidentate Nitrogen-Based Ligands and Their Application in Catalytic Dehydrogenation of Ammonia Borane

doi:10.6023/cjoc201805050

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (12): 3286-3295.DOI: 10.6023/cjoc201805050 Previous Articles Next Articles

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双齿N基配体锇配合物的合成及其在催化氨硼烷释氢中的应用

赵茜怡, 梁媛, 徐霆, 窦婷, 张絜, 陈学年

河南师范大学化学化工学院河南省硼化学与先进能源材料重点实验室新乡 453007

收稿日期:2018-05-28 修回日期:2018-07-10 发布日期:2018-08-14
通讯作者: 赵茜怡, 陈学年 E-mail:qyzhao@htu.edu.cn;xnchen@htu.edu.cn
基金资助:
国家自然科学基金（Nos.21501048，21503070，21571052，21771057）及河南省重点科技攻关（No.182102210377）资助项目.

Synthesis of Osmium Complexes with Bidentate Nitrogen-Based Ligands and Their Application in Catalytic Dehydrogenation of Ammonia Borane

Zhao Qianyi, Liang Yuan, Xu Ting, Dou Ting, Zhang Jie, Chen Xuenian

School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang 453007

Received:2018-05-28 Revised:2018-07-10 Published:2018-08-14
Contact: 10.6023/cjoc201805050 E-mail:qyzhao@htu.edu.cn;xnchen@htu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21501048, 21503070, 21571052, 21771057) and the Key Science and Technology Project of Henan Province (No.182102210377).

1. Synthesis of Osmium Complexes with Bidentate Nitrogen-Based Ligands and Their Application in Catalytic Dehydrogenation of Ammonia Borane.PDF(4218KB)

Abstract

Reactions of OsCl₂(PPh₃)₃ (1) with bidentate nitrogen-based ligands at room temperature led to the formation of complexes OsCl₂(PPh₃)₂(diamine) (2~6) and OsCl₂(PPh₃)₂(Phen^*) (7~11). Complexes 2~11 showed high activity in the catalytic dehydrogenation of ammonia borane at 60℃, in THF/DME (V:V=1:1.6) solution with the catalyst loading of 5 mol%. Among all the catalysts, compound 4 demonstrated the highest catalytic activity, which represents the most efficient osmium catalyst in catalytic dehydrogenation of ammonia borane until now.

Key words: osmium, complex, synthesis, catalytic dehydrogenation, ammonia borane

Cite this article

Zhao Qianyi, Liang Yuan, Xu Ting, Dou Ting, Zhang Jie, Chen Xuenian. Synthesis of Osmium Complexes with Bidentate Nitrogen-Based Ligands and Their Application in Catalytic Dehydrogenation of Ammonia Borane[J]. Chin. J. Org. Chem., 2018, 38(12): 3286-3295.

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双齿N基配体锇配合物的合成及其在催化氨硼烷释氢中的应用

Synthesis of Osmium Complexes with Bidentate Nitrogen-Based Ligands and Their Application in Catalytic Dehydrogenation of Ammonia Borane

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