Molecule-Responsive Supramolecular Hydrogel Constructed from Pillar[5]arene Based on Host-Guest System

doi:10.6023/cjoc201907042

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (1): 175-180.DOI: 10.6023/cjoc201907042 Previous Articles Next Articles

基于柱[5]芳烃主客体包结构筑分子响应型超分子水凝胶

王姣, 姚虹, 周琦, 阚晓彤, 樊彦青, 关晓文, 张有明, 林奇, 魏太保

西北师范大学化学化工学院甘肃省生态环境高分子材料重点实验室生态功能高分子材料教育部重点实验室兰州 730070

收稿日期:2019-07-27 修回日期:2019-09-07 发布日期:2019-09-18
通讯作者: 姚虹, 魏太保 E-mail:yhxbz@126.com;weitaibao@126.com
基金资助:
国家自然科学基金（Nos.21662031，21661028，21574104）资助项目.

Molecule-Responsive Supramolecular Hydrogel Constructed from Pillar[5]arene Based on Host-Guest System

Wang Jiao, Yao Hong, Zhou Qi, Kan Xiaotong, Fan Yanqing, Guan Xiaowen, Zhang Youming, Lin Qi, Wei Taibao

Key Laboratory of Eco-environmental Polymer Materials of Gansu Province, Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Received:2019-07-27 Revised:2019-09-07 Published:2019-09-18
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21662031, 21661028, 21574104).

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Abstract

The host-guest interaction was qualified as an ideal drive force to form stable inclusion complexes with macrocyclic host molecules in aqueous solution. Herein, a multi-responsive supramolecular hydrogel was constructed based on a functionalized benzimidazole derivative guest (M) with soluble pillar[5]arene as a host group. The mechanism of hydrogel formation was explored by the ¹H NMR, 2D NOESY and scanning electron microscope (SEM) in depth study. Interestingly, host-guest inclusion, the ordered "exo-wall" π-π interaction and hierarchical stacking of pillar[5]arene was indispensable to obtain the supramolecular hydrogel, which endowed the gel system with response to temperature change/chemical stimuli. Upon addition of competitive guests adiponitrile (ADN)/paraquat (PQ), pillar[5]arene-based hydrogel could be converted into sol. Herein, the organic molecules could be selectively recognized by the hydrogel.

Key words: supramolecular hydrogel, soluble pillar[5]arene, competitive inclusion, molecular recognition, self assembly

Cite this article

Wang Jiao, Yao Hong, Zhou Qi, Kan Xiaotong, Fan Yanqing, Guan Xiaowen, Zhang Youming, Lin Qi, Wei Taibao. Molecule-Responsive Supramolecular Hydrogel Constructed from Pillar[5]arene Based on Host-Guest System[J]. Chinese Journal of Organic Chemistry, 2020, 40(1): 175-180.

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基于柱[5]芳烃主客体包结构筑分子响应型超分子水凝胶

Molecule-Responsive Supramolecular Hydrogel Constructed from Pillar[5]arene Based on Host-Guest System

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